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- W2076456820 abstract "An important research area in proton exchange membrane fuel cells (PEMFC) is devoted to the development of low cost membranes able to work at temperatures higher than 100 °C. In this work, homogeneous, transparent and crack-free hybrid membranes have been synthesized using tetraethyl orthosilicate (TEOS), 3-glycidoxipropyl trimethoxysilane (GPTMS) and 2-allylphenol (AP) as precursors. The synthesis of proton conducting membranes was performed by a post-sulfonation method using trimethylsilyl chlorosulfonate as a mild sulfonating agent. The water retention properties provided by sulfonate and hydroxyl groups and the high porosity leads to relatively high proton conductivity (maximum values around 1.3 × 10−3 S cm−1 at 140 °C and 100% RH) for membranes treated at 180 °C and sulfonated for 2 h." @default.
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- W2076456820 date "2009-07-01" @default.
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- W2076456820 title "Proton conducting sol–gel sulfonated membranes produced from 2-allylphenol, 3-glycidoxypropyl trimethoxysilane and tetraethyl orthosilicate" @default.
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- W2076456820 doi "https://doi.org/10.1016/j.jpowsour.2008.12.126" @default.
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