Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076456838> ?p ?o ?g. }
- W2076456838 endingPage "696" @default.
- W2076456838 startingPage "696" @default.
- W2076456838 abstract "Recently, there is a rising interest in dissolving a variety of carbohydrates (such as sugars, starch and cellulose) in ionic liquids (ILs). The solutions of carbohydrates are then conveniently subject to chemical or physical modifications. However, one serious disadvantage of these ILs is their strong tendency in denaturing enzymes. This drawback prohibits the dissolved carbohydrates from being transformed by enzymatic reactions. In the present study, we designed a series of ILs that are able to dissolve carbohydrates but do not considerably inactivate the immobilized lipase B from Candida antarctica. These ILs consist of glycol-substituted cations and acetate anions. They could dissolve more than 10% (wt) cellulose and up to 80% (wt) D-glucose. The transesterification activities of the lipase in these ILs are very comparable with those in hydrophobic ILs. The hydrogen-bond forming anions, oxygen-containing cations, and low cation bulkiness promote the carbohydrate dissolution, while the low anion concentration appears essential for the enzyme stabilization. Therefore, an optimization could be achieved through a fine design of IL structures. To demonstrate the potential applications of these ILs, we performed the enzymatic transesterifications of methyl methacrylate with D-glucose and cellulose, respectively, both fully dissolved in ionic media. In the case of D-glucose, conversions up to 80% were obtained; and in the case of cellulose, conversions up to 89% and isolated yields up to 66% were achieved." @default.
- W2076456838 created "2016-06-24" @default.
- W2076456838 creator A5002581100 @default.
- W2076456838 creator A5017102844 @default.
- W2076456838 creator A5032575983 @default.
- W2076456838 creator A5040703058 @default.
- W2076456838 creator A5064269636 @default.
- W2076456838 creator A5069476345 @default.
- W2076456838 date "2008-01-01" @default.
- W2076456838 modified "2023-10-12" @default.
- W2076456838 title "Designing enzyme-compatible ionic liquids that can dissolve carbohydrates" @default.
- W2076456838 cites W1890330854 @default.
- W2076456838 cites W1964446240 @default.
- W2076456838 cites W1971266663 @default.
- W2076456838 cites W1974738281 @default.
- W2076456838 cites W1979838587 @default.
- W2076456838 cites W1980836177 @default.
- W2076456838 cites W1983496093 @default.
- W2076456838 cites W1984769267 @default.
- W2076456838 cites W1990627763 @default.
- W2076456838 cites W1992293247 @default.
- W2076456838 cites W1993990814 @default.
- W2076456838 cites W1997339946 @default.
- W2076456838 cites W1997481137 @default.
- W2076456838 cites W1999499045 @default.
- W2076456838 cites W2000613124 @default.
- W2076456838 cites W2002151871 @default.
- W2076456838 cites W2005742508 @default.
- W2076456838 cites W2007588434 @default.
- W2076456838 cites W2011287317 @default.
- W2076456838 cites W2012226596 @default.
- W2076456838 cites W2012271082 @default.
- W2076456838 cites W2021287806 @default.
- W2076456838 cites W2022253452 @default.
- W2076456838 cites W2023729590 @default.
- W2076456838 cites W2026585856 @default.
- W2076456838 cites W2026829023 @default.
- W2076456838 cites W2030795605 @default.
- W2076456838 cites W2031171862 @default.
- W2076456838 cites W2031676584 @default.
- W2076456838 cites W2033219642 @default.
- W2076456838 cites W2035145085 @default.
- W2076456838 cites W2035248003 @default.
- W2076456838 cites W2042190976 @default.
- W2076456838 cites W2042746129 @default.
- W2076456838 cites W2046271296 @default.
- W2076456838 cites W2048098509 @default.
- W2076456838 cites W2050507186 @default.
- W2076456838 cites W2054141268 @default.
- W2076456838 cites W2057536928 @default.
- W2076456838 cites W2058408007 @default.
- W2076456838 cites W2060151241 @default.
- W2076456838 cites W2065297660 @default.
- W2076456838 cites W2066134512 @default.
- W2076456838 cites W2066720071 @default.
- W2076456838 cites W2068100174 @default.
- W2076456838 cites W2070175333 @default.
- W2076456838 cites W2072823753 @default.
- W2076456838 cites W2073353689 @default.
- W2076456838 cites W2083701529 @default.
- W2076456838 cites W2085193495 @default.
- W2076456838 cites W2090750768 @default.
- W2076456838 cites W2094785339 @default.
- W2076456838 cites W2097501112 @default.
- W2076456838 cites W2125519621 @default.
- W2076456838 cites W2136772392 @default.
- W2076456838 cites W2138052893 @default.
- W2076456838 cites W2139774834 @default.
- W2076456838 cites W2150646833 @default.
- W2076456838 cites W2153076638 @default.
- W2076456838 cites W2155649389 @default.
- W2076456838 cites W2165861896 @default.
- W2076456838 cites W2169991758 @default.
- W2076456838 cites W2951469659 @default.
- W2076456838 cites W4379373312 @default.
- W2076456838 doi "https://doi.org/10.1039/b801489b" @default.
- W2076456838 hasPublicationYear "2008" @default.
- W2076456838 type Work @default.
- W2076456838 sameAs 2076456838 @default.
- W2076456838 citedByCount "421" @default.
- W2076456838 countsByYear W20764568382012 @default.
- W2076456838 countsByYear W20764568382013 @default.
- W2076456838 countsByYear W20764568382014 @default.
- W2076456838 countsByYear W20764568382015 @default.
- W2076456838 countsByYear W20764568382016 @default.
- W2076456838 countsByYear W20764568382017 @default.
- W2076456838 countsByYear W20764568382018 @default.
- W2076456838 countsByYear W20764568382019 @default.
- W2076456838 countsByYear W20764568382020 @default.
- W2076456838 countsByYear W20764568382021 @default.
- W2076456838 countsByYear W20764568382022 @default.
- W2076456838 countsByYear W20764568382023 @default.
- W2076456838 crossrefType "journal-article" @default.
- W2076456838 hasAuthorship W2076456838A5002581100 @default.
- W2076456838 hasAuthorship W2076456838A5017102844 @default.
- W2076456838 hasAuthorship W2076456838A5032575983 @default.
- W2076456838 hasAuthorship W2076456838A5040703058 @default.
- W2076456838 hasAuthorship W2076456838A5064269636 @default.