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• W2076457635 abstract "Enantioselective synthesis of the enantiomer of caloundrin B was achieved by strategic aldol coupling of an enantiopure trioxaadamantane-containing ketone with a racemic pyrone-containing aldehyde via kinetic resolution. In the presence of imidazole, ent-caloundrin B is cleanly isomerized to ent-siphonarin B confirming the proposed structure and absolute configuration for caloundrin B and establishing that it is a plausible biosynthetic product from which siphonarin B and baconipyrones A and C can originate." @default.
• W2076457635 created "2016-06-24" @default.
• W2076457635 creator A5033698362 @default.
• W2076457635 creator A5039619238 @default.
• W2076457635 date "2012-02-27" @default.
• W2076457635 modified "2023-10-18" @default.
• W2076457635 title "On the Origin of Siphonariid Polypropionates: Total Synthesis of Caloundrin B and Its Isomerization to Siphonarin B" @default.
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• W2076457635 doi "https://doi.org/10.1021/ol300432y" @default.
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