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- W2076463095 abstract "Abstract The ultimate elongation of vulcanized rubbers attains its maximum at a temperature Tmax, which was found to be sensitively increasing with increasing sequence regularity of alternating BD-AN copolymers and with increasing length of hard block of BD-ST block copolymers. Two kinds of rupture are proposed: a brittle rupture at low temperature occurs when the chain is extended fully and a plastic rupture occurs when the loosening of the chain caused by bond scission becomes faster than elongation. In the former case αb ∝ 1/αη˙, whereas in the latter αb ∝ 1/ατ˙, η and τ being resistance to viscous slippage and bond scission, respectively. It is estimated that Tmax decreases with increasing the crosslinks as well as the amorphous part, similar to a melting point." @default.
- W2076463095 created "2016-06-24" @default.
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- W2076463095 date "1973-03-01" @default.
- W2076463095 modified "2023-09-28" @default.
- W2076463095 title "Temperature Dependence of Ultimate Strength and Elongation of Vulcanized Rubber" @default.
- W2076463095 doi "https://doi.org/10.5254/1.3545015" @default.
- W2076463095 hasPublicationYear "1973" @default.
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