FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076467402> ?p ?o ?g. }

• W2076467402 endingPage "3931" @default.
• W2076467402 startingPage "3921" @default.
• W2076467402 abstract "Amine/silica/polymer composite hollow fiber adsorbents are produced using a novel reactive post-spinning infusion technique, and the obtained fibers are shown to capture CO2 from simulated flue gas. The post-spinning infusion technique allows for functionalization of polymer/silica hollow fibers with different types of amines during the solvent exchange step after fiber spinning. The post-spinning infusion of 3-aminopropyltrimethoxysilane (APS) into mesoporous silica/cellulose acetate hollow fibers is demonstrated here, and the materials are compared with hollow fibers infused with poly(ethyleneimine) (PEI). This approach results in silica/polymer composite fibers with good amine distribution and accessibility, as well as adequate porosity retained within the fibers to facilitate rapid mass transfer and adsorption kinetics. The CO2 adsorption capacities for the APS-infused hollow fibers are shown to be comparable to those of amine powders with similar amine loadings. In contrast, fibers that are spun with presynthesized, amine-loaded mesoporous silica powders show negligible CO2 uptake and low amine loadings because of loss of amines from the silica materials during the fiber spinning process. Aminosilica powders are shown to be more hydrophilic than the corresponding amine containing composite hollow fibers, the bare polymer as well as silica support. Both the PEI-infused and APS-infused fibers demonstrate reduced CO2 adsorption upon elevating the temperature from 35 to 80 °C, in accordance with thermodynamics, whereas PEI-infused powders show increased CO2 uptake over that temperature range because of competing diffusional and thermodynamic effects. The CO2 adsorption kinetics as probed via TGA show that the APS-infused hollow fiber adsorbents have more rapid uptake kinetics than their aminosilica powder analogues. The adsorption performance of the functionalized hollow fibers is also assessed in CO2 breakthrough experiments. The breakthrough results show a sharp CO2 front for APS-grafted fibers, indicating fast kinetics with comparable pseudo-equilibrium capacities to the CO2 equilibrium capacities measured via thermogravimetric analysis (TGA). The results indicate the post-spinning infusion method provides a new platform for synthesizing composite polymer/silica/amine fibers that may facilitate the ultimate scale-up of practical fiber adsorbents for flue gas CO2 capture applications." @default.
• W2076467402 created "2016-06-24" @default.
• W2076467402 creator A5019296207 @default.
• W2076467402 creator A5021581245 @default.
• W2076467402 creator A5035496185 @default.
• W2076467402 creator A5040515268 @default.
• W2076467402 creator A5052807182 @default.
• W2076467402 creator A5074939741 @default.
• W2076467402 creator A5086266470 @default.
• W2076467402 date "2013-04-16" @default.
• W2076467402 modified "2023-10-18" @default.
• W2076467402 title "Aminosilane-Grafted Polymer/Silica Hollow Fiber Adsorbents for CO₂ Capture from Flue Gas" @default.
• W2076467402 cites W100429331 @default.
• W2076467402 cites W1967743582 @default.
• W2076467402 cites W1973328341 @default.
• W2076467402 cites W1980704616 @default.
• W2076467402 cites W1986223744 @default.
• W2076467402 cites W1988239144 @default.
• W2076467402 cites W1997292086 @default.
• W2076467402 cites W2002266840 @default.
• W2076467402 cites W2020224983 @default.
• W2076467402 cites W2021156719 @default.
• W2076467402 cites W2021521911 @default.
• W2076467402 cites W2024955006 @default.
• W2076467402 cites W2036287051 @default.
• W2076467402 cites W2041566541 @default.
• W2076467402 cites W2045995555 @default.
• W2076467402 cites W2050143220 @default.
• W2076467402 cites W2050520353 @default.
• W2076467402 cites W2054700856 @default.
• W2076467402 cites W2055698251 @default.
• W2076467402 cites W2058389884 @default.
• W2076467402 cites W2073662703 @default.
• W2076467402 cites W2076634509 @default.
• W2076467402 cites W2076949647 @default.
• W2076467402 cites W2079549396 @default.
• W2076467402 cites W2080288737 @default.
• W2076467402 cites W2089879160 @default.
• W2076467402 cites W2091280238 @default.
• W2076467402 cites W2104943417 @default.
• W2076467402 cites W2108623890 @default.
• W2076467402 cites W2136939531 @default.
• W2076467402 cites W2144603483 @default.
• W2076467402 cites W2149881251 @default.
• W2076467402 cites W2150479102 @default.
• W2076467402 cites W2151993017 @default.
• W2076467402 cites W2318775926 @default.
• W2076467402 cites W2321233750 @default.
• W2076467402 cites W2322448833 @default.
• W2076467402 cites W2322571820 @default.
• W2076467402 cites W2332893944 @default.
• W2076467402 cites W2333166233 @default.
• W2076467402 cites W2460330511 @default.
• W2076467402 cites W92369477 @default.
• W2076467402 doi "https://doi.org/10.1021/am400636c" @default.
• W2076467402 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23540568" @default.
• W2076467402 hasPublicationYear "2013" @default.
• W2076467402 type Work @default.
• W2076467402 sameAs 2076467402 @default.
• W2076467402 citedByCount "123" @default.
• W2076467402 countsByYear W20764674022013 @default.
• W2076467402 countsByYear W20764674022014 @default.
• W2076467402 countsByYear W20764674022015 @default.
• W2076467402 countsByYear W20764674022016 @default.
• W2076467402 countsByYear W20764674022017 @default.
• W2076467402 countsByYear W20764674022018 @default.
• W2076467402 countsByYear W20764674022019 @default.
• W2076467402 countsByYear W20764674022020 @default.
• W2076467402 countsByYear W20764674022021 @default.
• W2076467402 countsByYear W20764674022022 @default.
• W2076467402 crossrefType "journal-article" @default.
• W2076467402 hasAuthorship W2076467402A5019296207 @default.
• W2076467402 hasAuthorship W2076467402A5021581245 @default.
• W2076467402 hasAuthorship W2076467402A5035496185 @default.
• W2076467402 hasAuthorship W2076467402A5040515268 @default.
• W2076467402 hasAuthorship W2076467402A5052807182 @default.
• W2076467402 hasAuthorship W2076467402A5074939741 @default.
• W2076467402 hasAuthorship W2076467402A5086266470 @default.
• W2076467402 hasConcept C104779481 @default.
• W2076467402 hasConcept C115537861 @default.
• W2076467402 hasConcept C127413603 @default.
• W2076467402 hasConcept C131779359 @default.
• W2076467402 hasConcept C150394285 @default.
• W2076467402 hasConcept C154815118 @default.
• W2076467402 hasConcept C159985019 @default.
• W2076467402 hasConcept C161790260 @default.
• W2076467402 hasConcept C178790620 @default.
• W2076467402 hasConcept C185592680 @default.
• W2076467402 hasConcept C188027245 @default.
• W2076467402 hasConcept C192562407 @default.
• W2076467402 hasConcept C2777496208 @default.
• W2076467402 hasConcept C42360764 @default.
• W2076467402 hasConcept C519885992 @default.
• W2076467402 hasConcept C521977710 @default.
• W2076467402 hasConcept C54965259 @default.
• W2076467402 hasConcept C82776694 @default.
• W2076467402 hasConceptScore W2076467402C104779481 @default.
• W2076467402 hasConceptScore W2076467402C115537861 @default.

• next