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- W2076475552 abstract "A new phase $mathrm{BT}ensuremath{-}mathrm{C}mathrm{O}$ on Si(100), not accessible with thermal CO (which leads to the $Tensuremath{-}mathrm{C}mathrm{O}$ phase), has been observed using an energetic molecular beam of CO and characterized by first principles quantum chemical methods. The $mathrm{BT}$ phase is composed of bridge $(B)$ and terminal $(T)$ sites; it is driven and stabilized by cooperative electrostatic interactions that result because $B$ $(T)$ binding leads to the transfer of charge away from (toward) the surface. Desorption of CO from the $B$ site proceeds through the $T$ configuration." @default.
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- W2076475552 date "1997-02-10" @default.
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- W2076475552 title "Nonthermally Accessible Phase for CO on the Si(100) Surface" @default.
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- W2076475552 doi "https://doi.org/10.1103/physrevlett.78.1178" @default.
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