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• W2076507741 abstract "A Pd-catalyzed asymmetric allylic alkylation of 2-substituted cycloalkenyl carbonates using a chiral diaminophosphine oxide is described. Asymmetric allylic substitution of various cyclic substrates proceeded using 5 mol % of Pd catalyst, 10 mol % of (S,RP)-Ph-DIAPHOX 1, 10 mol % of LiOAc, and N,O-bis(trimethylsilyl)acetamide (BSA), to afford the corresponding products in excellent yields with up to 92% ee." @default.
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• W2076507741 date "2008-05-01" @default.
• W2076507741 modified "2023-09-23" @default.
• W2076507741 title "Pd-catalyzed asymmetric allylic alkylation of 2-substituted cycloalkenyl carbonates using a chiral diaminophosphine oxide: (S,RP)-Ph-DIAPHOX" @default.
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• W2076507741 doi "https://doi.org/10.1016/j.tetasy.2008.03.027" @default.
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