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- W2076509953 abstract "Abstract Mechanistic aspects of electrochemical transformations of polyvinylidenefluoride (PVDF), polyvinylfluoride (PVF), copolymers of vinylidenefluoride (VDF) with tetrafluoroethylene (TFE) and hexa-fluoropropylene (HFP) at a cathodes of different nature in dimethylformamide in the presence of 0, 1 M (C4H9)4NCIO4 have been investigated. It is found that hydrogenfluorocontaining links of the copolymers, PVF and PVDF are able to dehydrofluorination at a cathode in investigated conditions. The main reason of this is an attack of macromolecules by negatively charged nucleophilic products that are formed at the dimethylformamide electrochemical reduction. Perfluorinative TFE and HFP links undergo direct electrochemical reduction through two irreversible stages with subsequent fluorine anions elimination and polyconjugated bonds formation. Based on the electrochemical and spectral data two different mechanisms of fluorocontaining carbochain polymers transformation at a cathode were suggested. On the whole, the obtained data testify to the possibility of an employment of polymer electrohemical transformations to realize their functionalization." @default.
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- W2076509953 date "1995-07-01" @default.
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- W2076509953 title "Electrochemically Induced Functionalization of Fluorocontaining Polyolefins" @default.
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- W2076509953 doi "https://doi.org/10.1080/10601329508018951" @default.
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