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- W2076538504 abstract "The adsorption behavior of polymer mixtures containing various styrene (S) and butadiene (B) polymers has been examined at 25°C using flame-hydrolyzed silica as the adsorbent and perchloroethylene (C2C14) as the solvent. The silica particle size and molecular weights of the polymers involved were varied. It was found that silica preferentially adsorbs polystyrene (PS) relative to polybutadiene (PBD) from C2C14. This effect is attributed to a stronger interaction of the styrene segments with the silica surface sites and not geometric or molecular sieve effects. Experiments with mixtures containing S/B di-block or S/B/S tri-block copolymers established that PS is preferentially adsorbed relative to either type of block. Displacement experiments showed that PBD is rapidly displaced by S/B/S tri-block and S/B/S tri-block is displaced by PS. These results suggest that adsorption experiments can be used to characterize block copolymer samples with regard to their homopolymer content." @default.
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- W2076538504 date "1973-12-01" @default.
- W2076538504 modified "2023-09-24" @default.
- W2076538504 title "The adsorption behavior of mixtures of styrene and butadiene polymers" @default.
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- W2076538504 doi "https://doi.org/10.1016/0021-9797(73)90167-7" @default.
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