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- W2076545424 abstract "The morphotropic composition of lead zirconate titanate (PZT), ${mathrm{PbZr}}_{0.52}{mathrm{Ti}}_{0.48}{mathrm{O}}_{3}$, was studied as a function of temperature $(47--310phantom{rule{0.3em}{0ex}}mathrm{K})$ and hydrostatic pressure (from $0.1phantom{rule{0.3em}{0ex}}mathrm{MPa}$ to $7.6phantom{rule{0.3em}{0ex}}mathrm{GPa}$) by neutron powder diffraction. Series of monoclinic (space groups $Cm$ and $Cc$) and triclinic phases (space groups $F1$ and $Foverline{1}$) were observed at various points in the $Ptext{ensuremath{-}}T$ phase diagram of ${mathrm{PbZr}}_{0.52}{mathrm{Ti}}_{0.48}{mathrm{O}}_{3}$. The high-pressure behavior is characterized by two mechanisms, a rotation and reduction of the spontaneous polarization and the onset of octahedral tilting leading to unit cell doubling. The results show that pressure, as in the case of temperature and external electric fields, can induce polarization rotation." @default.
- W2076545424 created "2016-06-24" @default.
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- W2076545424 date "2005-01-21" @default.
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- W2076545424 title "Pressure-induced rotation of spontaneous polarization in monoclinic and triclinic<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>PbZr</mml:mi></mml:mrow><mml:mrow><mml:mn>0.52</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mi mathvariant=normal>Ti</mml:mi></mml:mrow><mml:mrow><mml:mn>0.48</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mi mathvariant=normal>O</mml:mi><mml:mn>3</mml:mn></mml:…" @default.
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- W2076545424 doi "https://doi.org/10.1103/physrevb.71.024112" @default.
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