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- W2076569817 abstract "Ten new dioxovanadium(V) complexes incorporating Schiff bases derived from (S)-(+)-2-(aminomethyl)pyrrolidine and aromatic o-hydroxycarbonyl compounds were synthesized and investigated by spectroscopic methods. The X-ray experiment on N-(methylsalicylidene)-(S)-(2-pyrrolidinylmethyl)amine dioxovanadium(V) monohydrate shows that the crystal of that compound is a solid solution of two diastereomers, which differ in conformation of five-membered rings and in absolute configuration of the chiral centre containing the asymmetric carbon atom. The weak predominance in content of S-diastereomer over R-diastereomer in the crystal (55:45) increases strongly in DMSO solution (75:25), as evidenced by 1H and 51V NMR studies, indicating that the crystallization induces the asymmetric transformation of S-diastereomer. The free energy of transformation of S-diastereomer into its R analog in DMSO solution is particularly low for complexes containing ethylidene substituent attached to the aromatic ring." @default.
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- W2076569817 date "2006-11-01" @default.
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- W2076569817 title "Dioxovanadium(V) complexes of Schiff bases derived from S-(+)-2-(aminomethyl)pyrrolidine and aromatic o-hydroxycarbonyl compounds: Synthesis, characterization and structure" @default.
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- W2076569817 doi "https://doi.org/10.1016/j.poly.2006.04.004" @default.
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