Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076573676> ?p ?o ?g. }
- W2076573676 abstract "By means of integrated and dispersed IR photon echo measurement methods, the vibrational dynamics of C-N stretch modes in 4-cyanophenol and 4-cyanophenoxide in methanol is investigated. The vibrational frequency-frequency correlation function (FFCF) is retrieved from the integrated photon echo signals by assuming that the FFCF is described by two exponential functions with about 400 fs and a few picosecond components. The excited state lifetimes of the C-N stretch modes of neutral and anionic 4-cyanophenols are 1.45 and 0.91 ps, respectively, and the overtone anharmonic frequency shifts are 25 and 28 cm(-1). At short waiting times, a notable underdamped oscillation, which is attributed to a low-frequency intramolecular vibration coupled to the CN stretch, in the integrated and dispersed vibrational echo as well as transient grating signals was observed. The spectral bandwidths of IR absorption and dispersed vibrational echo spectra of the 4-cyanophenoxide are significantly larger than those of its neutral form, indicating that the strong interaction between phenoxide and methanol causes large frequency fluctuation and rapid population relaxation. The resonance effects in a paradisubstituted aromatic compound would be of interest in understanding the conjugation effects and their influences on chemical reactivity of various aromatic compounds in organic solvents." @default.
- W2076573676 created "2016-06-24" @default.
- W2076573676 creator A5023502885 @default.
- W2076573676 creator A5027685378 @default.
- W2076573676 creator A5030007632 @default.
- W2076573676 creator A5058547990 @default.
- W2076573676 creator A5063078837 @default.
- W2076573676 creator A5070496831 @default.
- W2076573676 date "2009-05-27" @default.
- W2076573676 modified "2023-09-27" @default.
- W2076573676 title "Integrated and dispersed photon echo studies of nitrile stretching vibration of 4-cyanophenol in methanol" @default.
- W2076573676 cites W1674305514 @default.
- W2076573676 cites W1800057439 @default.
- W2076573676 cites W1965657762 @default.
- W2076573676 cites W1966332661 @default.
- W2076573676 cites W1967097202 @default.
- W2076573676 cites W1969325779 @default.
- W2076573676 cites W1970979585 @default.
- W2076573676 cites W1971526188 @default.
- W2076573676 cites W1972095648 @default.
- W2076573676 cites W1973223428 @default.
- W2076573676 cites W1973626565 @default.
- W2076573676 cites W1977276027 @default.
- W2076573676 cites W1979211933 @default.
- W2076573676 cites W1984932308 @default.
- W2076573676 cites W1994448876 @default.
- W2076573676 cites W1998663208 @default.
- W2076573676 cites W2003440615 @default.
- W2076573676 cites W2015467449 @default.
- W2076573676 cites W2015624811 @default.
- W2076573676 cites W2017805558 @default.
- W2076573676 cites W2020834701 @default.
- W2076573676 cites W2023053975 @default.
- W2076573676 cites W2026073071 @default.
- W2076573676 cites W2026923622 @default.
- W2076573676 cites W2029550067 @default.
- W2076573676 cites W2029799575 @default.
- W2076573676 cites W2030140216 @default.
- W2076573676 cites W2030611733 @default.
- W2076573676 cites W2031151041 @default.
- W2076573676 cites W2033947791 @default.
- W2076573676 cites W2035473765 @default.
- W2076573676 cites W2056622041 @default.
- W2076573676 cites W2056926980 @default.
- W2076573676 cites W2057828433 @default.
- W2076573676 cites W2058006670 @default.
- W2076573676 cites W2061393940 @default.
- W2076573676 cites W2062095590 @default.
- W2076573676 cites W2063887600 @default.
- W2076573676 cites W2064630425 @default.
- W2076573676 cites W2067174909 @default.
- W2076573676 cites W2069805585 @default.
- W2076573676 cites W2071558544 @default.
- W2076573676 cites W2071638281 @default.
- W2076573676 cites W2071644911 @default.
- W2076573676 cites W2076108307 @default.
- W2076573676 cites W2080987910 @default.
- W2076573676 cites W2084402536 @default.
- W2076573676 cites W2084582300 @default.
- W2076573676 cites W2087088685 @default.
- W2076573676 cites W2089865495 @default.
- W2076573676 cites W2090895096 @default.
- W2076573676 cites W2092758119 @default.
- W2076573676 cites W2095231306 @default.
- W2076573676 cites W2104283260 @default.
- W2076573676 cites W2130119647 @default.
- W2076573676 cites W2136751388 @default.
- W2076573676 cites W2145764349 @default.
- W2076573676 cites W2147443012 @default.
- W2076573676 cites W2492361948 @default.
- W2076573676 cites W4214510387 @default.
- W2076573676 doi "https://doi.org/10.1063/1.3140402" @default.
- W2076573676 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19485459" @default.
- W2076573676 hasPublicationYear "2009" @default.
- W2076573676 type Work @default.
- W2076573676 sameAs 2076573676 @default.
- W2076573676 citedByCount "21" @default.
- W2076573676 countsByYear W20765736762013 @default.
- W2076573676 countsByYear W20765736762014 @default.
- W2076573676 countsByYear W20765736762016 @default.
- W2076573676 countsByYear W20765736762017 @default.
- W2076573676 countsByYear W20765736762018 @default.
- W2076573676 countsByYear W20765736762019 @default.
- W2076573676 countsByYear W20765736762021 @default.
- W2076573676 countsByYear W20765736762022 @default.
- W2076573676 crossrefType "journal-article" @default.
- W2076573676 hasAuthorship W2076573676A5023502885 @default.
- W2076573676 hasAuthorship W2076573676A5027685378 @default.
- W2076573676 hasAuthorship W2076573676A5030007632 @default.
- W2076573676 hasAuthorship W2076573676A5058547990 @default.
- W2076573676 hasAuthorship W2076573676A5063078837 @default.
- W2076573676 hasAuthorship W2076573676A5070496831 @default.
- W2076573676 hasConcept C120665830 @default.
- W2076573676 hasConcept C121332964 @default.
- W2076573676 hasConcept C1276947 @default.
- W2076573676 hasConcept C139210041 @default.
- W2076573676 hasConcept C144024400 @default.
- W2076573676 hasConcept C147724859 @default.
- W2076573676 hasConcept C149923435 @default.
- W2076573676 hasConcept C153642686 @default.