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- W2076576516 abstract "The Tavorite-type composition LiVPO4F undergoes a complex series of phase transformations upon Li+ electrochemical extraction or insertion at ∼4.25 V (V4+/V3+ redox couple) and 1.8 V vs. Li (V3+/V2+ redox couple), respectively. In all the reactions involved, followed by in-house in situ X-Ray diffraction, two-phase topotactic mechanisms are systematically encountered, without noticeable modification of the [VPO4F] framework besides significant unit-cell contractions/expansions and overall shifts in symmetry from triclinic P-1 to monoclinic C2/c. Two electrochemical oxidation reactions occur at 4.24 V and 4.28 V vs. Li due to the formation of the intermediate phase Li0.67VPO4F, isolated for the first time. Noticeably, this peculiar composition is not encountered upon reduction from VPO4F to LiVPO4F." @default.
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- W2076576516 date "2012-01-01" @default.
- W2076576516 modified "2023-10-11" @default.
- W2076576516 title "Lithium Insertion or Extraction from/into Tavorite-Type LiVPO<sub>4</sub>F: An In Situ X-ray Diffraction Study" @default.
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- W2076576516 doi "https://doi.org/10.1149/2.022208jes" @default.
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