FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076581211> ?p ?o ?g. }

• W2076581211 endingPage "943" @default.
• W2076581211 startingPage "933" @default.
• W2076581211 abstract "The formation of chitosan physical hydrogels without any external cross-linking agent was studied. This gelation took place in an acetic acid-water-propanediol solution. Static light scattering was used to detect the gel point and then, to study the gelation for different initial conditions. Thus, we investigated the influence of the degree of acetylation, the gelation temperature and the nature of the initial solvent. The variation of the solvent composition during gelation was determined from a simple weighting, and the ionisation state of the polymer at the gel point, by pH titrations. This work showed that it was possible to form a chitosan physical-hydrogel, whatever the degree of acetylation provided typical conditions were observed. The mechanism of gelation simply consisted in the modification of the hydrophilic/hydrophobic balance allowing the formation of both hydrophobic interactions and hydrogen bonding. Several parameters had an important role on this mechanism: 1--the apparent charge density of chitosan, modified by the degree of neutralisation, 2--the dielectric constant of the solvent, related to the composition of the medium, 3--the degree of acetylation, 4--temperature, playing a role on the interactions responsible for the physical cross-linking and the molecular mobility, and, 5--the molecular mobility depending on possible changes of conformation, steric hindrance and viscosity of the medium." @default.
• W2076581211 created "2016-06-24" @default.
• W2076581211 creator A5036446726 @default.
• W2076581211 creator A5062627265 @default.
• W2076581211 creator A5074783585 @default.
• W2076581211 date "2005-03-01" @default.
• W2076581211 modified "2023-10-16" @default.
• W2076581211 title "Physico-chemical studies of the gelation of chitosan in a hydroalcoholic medium" @default.
• W2076581211 cites W1563077016 @default.
• W2076581211 cites W1967666993 @default.
• W2076581211 cites W1979125837 @default.
• W2076581211 cites W1983144574 @default.
• W2076581211 cites W1985733170 @default.
• W2076581211 cites W1986591269 @default.
• W2076581211 cites W1988525414 @default.
• W2076581211 cites W1995175553 @default.
• W2076581211 cites W1999968637 @default.
• W2076581211 cites W2010166151 @default.
• W2076581211 cites W2015589806 @default.
• W2076581211 cites W2015943769 @default.
• W2076581211 cites W2020322655 @default.
• W2076581211 cites W2021499496 @default.
• W2076581211 cites W2023162805 @default.
• W2076581211 cites W2025255050 @default.
• W2076581211 cites W2030666347 @default.
• W2076581211 cites W2036547133 @default.
• W2076581211 cites W2037255761 @default.
• W2076581211 cites W2037912605 @default.
• W2076581211 cites W2048381378 @default.
• W2076581211 cites W2051243038 @default.
• W2076581211 cites W2059006813 @default.
• W2076581211 cites W2064908148 @default.
• W2076581211 cites W2073571039 @default.
• W2076581211 cites W2079822872 @default.
• W2076581211 cites W2085986601 @default.
• W2076581211 cites W2090497782 @default.
• W2076581211 cites W2090890372 @default.
• W2076581211 cites W2091824651 @default.
• W2076581211 cites W2324658904 @default.
• W2076581211 cites W2416922689 @default.
• W2076581211 cites W2520543507 @default.
• W2076581211 cites W2760110999 @default.
• W2076581211 doi "https://doi.org/10.1016/j.biomaterials.2004.03.033" @default.
• W2076581211 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15353205" @default.
• W2076581211 hasPublicationYear "2005" @default.
• W2076581211 type Work @default.
• W2076581211 sameAs 2076581211 @default.
• W2076581211 citedByCount "112" @default.
• W2076581211 countsByYear W20765812112012 @default.
• W2076581211 countsByYear W20765812112013 @default.
• W2076581211 countsByYear W20765812112014 @default.
• W2076581211 countsByYear W20765812112015 @default.
• W2076581211 countsByYear W20765812112016 @default.
• W2076581211 countsByYear W20765812112017 @default.
• W2076581211 countsByYear W20765812112018 @default.
• W2076581211 countsByYear W20765812112019 @default.
• W2076581211 countsByYear W20765812112020 @default.
• W2076581211 countsByYear W20765812112021 @default.
• W2076581211 countsByYear W20765812112022 @default.
• W2076581211 countsByYear W20765812112023 @default.
• W2076581211 crossrefType "journal-article" @default.
• W2076581211 hasAuthorship W2076581211A5036446726 @default.
• W2076581211 hasAuthorship W2076581211A5062627265 @default.
• W2076581211 hasAuthorship W2076581211A5074783585 @default.
• W2076581211 hasConcept C108586683 @default.
• W2076581211 hasConcept C112887158 @default.
• W2076581211 hasConcept C127172972 @default.
• W2076581211 hasConcept C127413603 @default.
• W2076581211 hasConcept C159985019 @default.
• W2076581211 hasConcept C178790620 @default.
• W2076581211 hasConcept C181199279 @default.
• W2076581211 hasConcept C184866935 @default.
• W2076581211 hasConcept C185592680 @default.
• W2076581211 hasConcept C188027245 @default.
• W2076581211 hasConcept C192562407 @default.
• W2076581211 hasConcept C201194858 @default.
• W2076581211 hasConcept C2779732960 @default.
• W2076581211 hasConcept C2780471494 @default.
• W2076581211 hasConcept C32909587 @default.
• W2076581211 hasConcept C42360764 @default.
• W2076581211 hasConcept C521977710 @default.
• W2076581211 hasConcept C96294017 @default.
• W2076581211 hasConceptScore W2076581211C108586683 @default.
• W2076581211 hasConceptScore W2076581211C112887158 @default.
• W2076581211 hasConceptScore W2076581211C127172972 @default.
• W2076581211 hasConceptScore W2076581211C127413603 @default.
• W2076581211 hasConceptScore W2076581211C159985019 @default.
• W2076581211 hasConceptScore W2076581211C178790620 @default.
• W2076581211 hasConceptScore W2076581211C181199279 @default.
• W2076581211 hasConceptScore W2076581211C184866935 @default.
• W2076581211 hasConceptScore W2076581211C185592680 @default.
• W2076581211 hasConceptScore W2076581211C188027245 @default.
• W2076581211 hasConceptScore W2076581211C192562407 @default.
• W2076581211 hasConceptScore W2076581211C201194858 @default.
• W2076581211 hasConceptScore W2076581211C2779732960 @default.
• W2076581211 hasConceptScore W2076581211C2780471494 @default.
• W2076581211 hasConceptScore W2076581211C32909587 @default.
• W2076581211 hasConceptScore W2076581211C42360764 @default.

• next