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• W2076593754 endingPage "8662" @default.
• W2076593754 startingPage "8645" @default.
• W2076593754 abstract "We have formulated a general approach for transforming an analytical equation of state (EOS) into the crossover form and developed a generalized cubic (GC) EOS for pure fluids, which incorporates nonanalytic scaling laws in the critical region and in the limit ρ→0 is transformed into the ideal gas equation EOS. Using the GC EOS as a reference equation, we have developed a generalized version of the corresponding states (GCS) model, which contains the critical point parameters and accentric factor as input as well as the Ginzburg number Gi. For nonionic fluids we propose a simple correlation between the Ginzburg number Gi and Zc, ω, and molecular weight Mw. In the second step, we develop on the basis of the GCS model and the density functional theory a GCS-density functional theory (DFT) crossover model for the vapor–liquid interface and surface tension. We use the GCS-DFT model for the prediction of the PVT, vapor–liquid equilibrium (VLE) and surface properties of more than 30 pure fluids. In a wide range of thermodynamic states, including the nearest vicinity of the critical point, the GCS reproduces the PVT and VLE surface and the surface tension of one-component fluids (polar and nonpolar) with high accuracy. In the critical region, the GCS-DFT predictions for the surface tension are in excellent agreement with experimental data and theoretical renormalization-group model developed earlier. Using the principle of the critical-point universality we extended the GCS-DFT model to fluid mixtures and developed a field-variable based GCS-FV model. We provide extensive comparisons of the GCS-FV model with experimental data and with the GCS-XV model formulated in terms of the conventional density variable—composition. Far from the critical point both models, GCS-FV and GCS-XV, give practically similar results, but in the critical region, the GCS-FV model yields a better representation of the VLE surface of binary mixtures than the GCS-XV model. We also show that by considering the Ginzburg number Gi as an independent CS parameter the GCS model is capable of reproducing the phase behavior of finite neutral nuclear matter." @default.
• W2076593754 created "2016-06-24" @default.
• W2076593754 creator A5057491040 @default.
• W2076593754 creator A5069390435 @default.
• W2076593754 date "2003-10-10" @default.
• W2076593754 modified "2023-09-26" @default.
• W2076593754 title "Generalized corresponding states model for bulk and interfacial properties in pure fluids and fluid mixtures" @default.
• W2076593754 cites W1480723740 @default.
• W2076593754 cites W1585401729 @default.
• W2076593754 cites W1633875241 @default.
• W2076593754 cites W1642705503 @default.
• W2076593754 cites W1842717037 @default.
• W2076593754 cites W1964387479 @default.
• W2076593754 cites W1965222543 @default.
• W2076593754 cites W1968294706 @default.
• W2076593754 cites W1969799177 @default.
• W2076593754 cites W1970387206 @default.
• W2076593754 cites W1971359061 @default.
• W2076593754 cites W1971577048 @default.
• W2076593754 cites W1971717672 @default.
• W2076593754 cites W1972174872 @default.
• W2076593754 cites W1978812815 @default.
• W2076593754 cites W1981431134 @default.
• W2076593754 cites W1986359208 @default.
• W2076593754 cites W1987422067 @default.
• W2076593754 cites W1988345083 @default.
• W2076593754 cites W1988696952 @default.
• W2076593754 cites W1991667731 @default.
• W2076593754 cites W1992623294 @default.
• W2076593754 cites W1992691508 @default.
• W2076593754 cites W1992764418 @default.
• W2076593754 cites W1993747455 @default.
• W2076593754 cites W1994063700 @default.
• W2076593754 cites W1995429797 @default.
• W2076593754 cites W1996991124 @default.
• W2076593754 cites W1998796594 @default.
• W2076593754 cites W1999486257 @default.
• W2076593754 cites W1999912367 @default.
• W2076593754 cites W2000365429 @default.
• W2076593754 cites W2005634679 @default.
• W2076593754 cites W2006531574 @default.
• W2076593754 cites W2007870851 @default.
• W2076593754 cites W2009878438 @default.
• W2076593754 cites W2012011337 @default.
• W2076593754 cites W2012282758 @default.
• W2076593754 cites W2014005724 @default.
• W2076593754 cites W2014385915 @default.
• W2076593754 cites W2014389937 @default.
• W2076593754 cites W2014754847 @default.
• W2076593754 cites W2015627558 @default.
• W2076593754 cites W2016385105 @default.
• W2076593754 cites W2017264618 @default.
• W2076593754 cites W2018779829 @default.
• W2076593754 cites W2018996505 @default.
• W2076593754 cites W2020002880 @default.
• W2076593754 cites W2022585738 @default.
• W2076593754 cites W2030411970 @default.
• W2076593754 cites W2030784559 @default.
• W2076593754 cites W2030862053 @default.
• W2076593754 cites W2031952333 @default.
• W2076593754 cites W2033803608 @default.
• W2076593754 cites W2033862127 @default.
• W2076593754 cites W2035717217 @default.
• W2076593754 cites W2036289499 @default.
• W2076593754 cites W2037459167 @default.
• W2076593754 cites W2037477299 @default.
• W2076593754 cites W2039259039 @default.
• W2076593754 cites W2040563899 @default.
• W2076593754 cites W2042365364 @default.
• W2076593754 cites W2043961228 @default.
• W2076593754 cites W2045008609 @default.
• W2076593754 cites W2045477234 @default.
• W2076593754 cites W2045605843 @default.
• W2076593754 cites W2046467996 @default.
• W2076593754 cites W2046885854 @default.
• W2076593754 cites W2049837541 @default.
• W2076593754 cites W2051085106 @default.
• W2076593754 cites W2051716669 @default.
• W2076593754 cites W2052794818 @default.
• W2076593754 cites W2053757863 @default.
• W2076593754 cites W2054461812 @default.
• W2076593754 cites W2055591744 @default.
• W2076593754 cites W2056162357 @default.
• W2076593754 cites W2057410850 @default.
• W2076593754 cites W2058457533 @default.
• W2076593754 cites W2060920459 @default.
• W2076593754 cites W2061424829 @default.
• W2076593754 cites W2061466944 @default.
• W2076593754 cites W2062390018 @default.
• W2076593754 cites W2064149230 @default.
• W2076593754 cites W2064350491 @default.
• W2076593754 cites W2066972517 @default.
• W2076593754 cites W2067934634 @default.
• W2076593754 cites W2068710164 @default.
• W2076593754 cites W2069060364 @default.
• W2076593754 cites W2069365997 @default.
• W2076593754 cites W2069717437 @default.
• W2076593754 cites W2071443733 @default.

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