Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076597873> ?p ?o ?g. }
- W2076597873 endingPage "6508" @default.
- W2076597873 startingPage "6501" @default.
- W2076597873 abstract "The excited-state dynamics of heteroleptic iridium(III) complexes have been investigated using femto-nanosecond time-resolved luminescence and transient absorption spectroscopy. Two prototypical examples illustrated here are iridium(III) bis[2-(2,4-difluorophenyl)pyridinato-N,C(2')] quinaldinate (1) and iridium(III) bis[2-(2,4-difluorophenyl)pyridinato-N,C(2')][2-(6-methylbenzoxazol-2-yl)phenolate] (2). Upon photoexcitation at, for example, 400 nm, the emission decay, monitored at the region of phosphorescence, for both 1 and 2 consists of a system response limited rise (<300 ps) and a single exponential decay. Further single wavelength as well as full spectrum of femto-picosecond transient absorption acquired in CH(2)Cl(2) at room temperature reveals an ultrafast S(1) --> T(n) intersystem crossing (<1 ps) and a rapid T(n) --> T(1) internal conversion/vibrational relaxation within a time period of <10 ps. The results lead us to conclude that following Franck-Condon excitation, the time scale required to populate the lowest triplet state should be <10 ps." @default.
- W2076597873 created "2016-06-24" @default.
- W2076597873 creator A5032004836 @default.
- W2076597873 creator A5033815508 @default.
- W2076597873 creator A5046992398 @default.
- W2076597873 creator A5075969864 @default.
- W2076597873 creator A5088949001 @default.
- W2076597873 date "2009-06-19" @default.
- W2076597873 modified "2023-09-26" @default.
- W2076597873 title "Photophysics of Heteroleptic Iridium(III) Complexes Of Current Interest; a Closer Look on Relaxation Dynamics" @default.
- W2076597873 cites W1485608166 @default.
- W2076597873 cites W1668566020 @default.
- W2076597873 cites W189827329 @default.
- W2076597873 cites W1966006624 @default.
- W2076597873 cites W1966182479 @default.
- W2076597873 cites W1970326168 @default.
- W2076597873 cites W1973284434 @default.
- W2076597873 cites W1980980562 @default.
- W2076597873 cites W1982461878 @default.
- W2076597873 cites W1984172934 @default.
- W2076597873 cites W1986380791 @default.
- W2076597873 cites W1989834263 @default.
- W2076597873 cites W1997474741 @default.
- W2076597873 cites W2000181483 @default.
- W2076597873 cites W2001205412 @default.
- W2076597873 cites W2007580576 @default.
- W2076597873 cites W2009416752 @default.
- W2076597873 cites W2016470740 @default.
- W2076597873 cites W2019265638 @default.
- W2076597873 cites W2020736879 @default.
- W2076597873 cites W2023271753 @default.
- W2076597873 cites W2029093078 @default.
- W2076597873 cites W2031301453 @default.
- W2076597873 cites W2035294969 @default.
- W2076597873 cites W2036703429 @default.
- W2076597873 cites W2038420860 @default.
- W2076597873 cites W2044490585 @default.
- W2076597873 cites W2044829561 @default.
- W2076597873 cites W2045146668 @default.
- W2076597873 cites W2052329392 @default.
- W2076597873 cites W2063663126 @default.
- W2076597873 cites W2068617439 @default.
- W2076597873 cites W2069197437 @default.
- W2076597873 cites W2070101361 @default.
- W2076597873 cites W2070235865 @default.
- W2076597873 cites W2071569358 @default.
- W2076597873 cites W2083230535 @default.
- W2076597873 cites W2085400086 @default.
- W2076597873 cites W2085989548 @default.
- W2076597873 cites W2090006202 @default.
- W2076597873 cites W2090229808 @default.
- W2076597873 cites W2095917356 @default.
- W2076597873 cites W2117770267 @default.
- W2076597873 cites W2119249051 @default.
- W2076597873 cites W2120436453 @default.
- W2076597873 cites W2123491942 @default.
- W2076597873 cites W2134192844 @default.
- W2076597873 cites W2143981217 @default.
- W2076597873 cites W2151256381 @default.
- W2076597873 cites W2151704214 @default.
- W2076597873 cites W2151954645 @default.
- W2076597873 doi "https://doi.org/10.1021/ic9003164" @default.
- W2076597873 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19537805" @default.
- W2076597873 hasPublicationYear "2009" @default.
- W2076597873 type Work @default.
- W2076597873 sameAs 2076597873 @default.
- W2076597873 citedByCount "42" @default.
- W2076597873 countsByYear W20765978732012 @default.
- W2076597873 countsByYear W20765978732013 @default.
- W2076597873 countsByYear W20765978732014 @default.
- W2076597873 countsByYear W20765978732015 @default.
- W2076597873 countsByYear W20765978732016 @default.
- W2076597873 countsByYear W20765978732017 @default.
- W2076597873 countsByYear W20765978732018 @default.
- W2076597873 countsByYear W20765978732019 @default.
- W2076597873 countsByYear W20765978732020 @default.
- W2076597873 countsByYear W20765978732022 @default.
- W2076597873 crossrefType "journal-article" @default.
- W2076597873 hasAuthorship W2076597873A5032004836 @default.
- W2076597873 hasAuthorship W2076597873A5033815508 @default.
- W2076597873 hasAuthorship W2076597873A5046992398 @default.
- W2076597873 hasAuthorship W2076597873A5075969864 @default.
- W2076597873 hasAuthorship W2076597873A5088949001 @default.
- W2076597873 hasBestOaLocation W20765978732 @default.
- W2076597873 hasConcept C116039458 @default.
- W2076597873 hasConcept C120665830 @default.
- W2076597873 hasConcept C121332964 @default.
- W2076597873 hasConcept C1276947 @default.
- W2076597873 hasConcept C155220765 @default.
- W2076597873 hasConcept C15744967 @default.
- W2076597873 hasConcept C161790260 @default.
- W2076597873 hasConcept C178790620 @default.
- W2076597873 hasConcept C181500209 @default.
- W2076597873 hasConcept C181817918 @default.
- W2076597873 hasConcept C184779094 @default.
- W2076597873 hasConcept C185592680 @default.
- W2076597873 hasConcept C2776029896 @default.
- W2076597873 hasConcept C32891209 @default.