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- W2076604493 abstract "The fraction of the dative structure, b2 + abS, of hydrogen bonded complexes of N,N-dimethylacetamide with phenol derivatives and of charge transfer complexes of some aliphatic amides with iodine, is computed from the displacement of some vibrational modes. The values of b2 + abS are computed from the vco frequency shifts using a limiting value of 6 · 105 dyne cm−1 for the value of the force constant of the carbonyl bond in the dative structure. In the case of hydrogen bonded complexes, these results are compared with values of b2 + abS computed from the ΔvOH stretching vibrations by the theory of Szczepaniak and Tramer. For the charge transfer complexes, the values of b2 + abS are computed from the v(I-I) stretching vibrations using the equation of Friedrich and Person. The agreement between the two methods is good in both cases." @default.
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- W2076604493 date "1975-06-01" @default.
- W2076604493 modified "2023-10-16" @default.
- W2076604493 title "Charge transfer properties of molecular complexes involving carbonyl bonds" @default.
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- W2076604493 doi "https://doi.org/10.1016/0022-2860(75)80016-0" @default.
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