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- W2076604877 abstract "The reaction of 2-propanol over various phosphorus-containing heteropolyacids was investigated as a function of pretreatment temperature and composition of the heteropolyacids. With catalysts pretreated at 100–300 °C, only propene was produced. However, after pretreatment at 450 °C, the selectivity changed in favor of acetone over some mixed molybdenum and tungsten heteropolyacids. From infrared (IR) and thermogravimetry-differential thermal analysis (TG-DTA) measurements, the improvement in acetone selectivity was ascribed to the destruction of Keggin units of the heteropolyacid. The maximum selectivity to acetone was observed for H3PMo12−xWxO40 whenx = 6." @default.
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- W2076604877 date "1991-10-01" @default.
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- W2076604877 title "Reaction of 2-propanol over heteropolyacids after pretreatment in air" @default.
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