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- W2076609358 abstract "Recently, it was shown that a Ni(I) complex with a tetraazamacrocyclic ligand (NiI(1, 4, 8, 11-tetraazacyclotetradecane)+, , cyclam), reduces maleate in aqueous solutions. It was decided to investigate whether this is a general reaction of low valent transition metal complexes. In this study, the reactions of CoIL+ (L = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) with maleate were investigated. The effect of the addition of maleate to aqueous solutions containing this low valent metal complex, prepared via the pulse radiolysis technique, was studied. The d → π* complexes formed between the monovalent cobalt complex and maleate were detected and characterized by UV-Vis spectroscopy. The nature of the final products formed was studied and detailed mechanisms of the reduction processes are proposed. The mechanism and kinetics of the reaction of Co(I)L+ with maleate was studied applying pulse-radiolysis and analysis of the final products." @default.
- W2076609358 created "2016-06-24" @default.
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- W2076609358 date "2010-07-13" @default.
- W2076609358 modified "2023-10-18" @default.
- W2076609358 title "On the mechanism of reduction of maleate by a Co(I) complex with a macrocylic ligand in aqueous solutions" @default.
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- W2076609358 doi "https://doi.org/10.1080/00958972.2010.499938" @default.
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