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• W2076611240 abstract "We report femtosecond direct pump/probe data on the s-state to p-state transition of the solvated electron in alcohols. The data reveal a p-state lifetime of ≈ 0.5 ps and a large spectral component due to displacement along the ground-state solvent coordinate involving slow diffusive solvent motions and subsequent relaxation. The large displacement is surprising considering the short excited-state lifetime and the long relaxation times of these modes. This effect is apparently the result of a previously unknown p-state to s-state nonadiabatic rearrangement of the solvent coordinate of solvated electrons in alcohols." @default.
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• W2076611240 date "1995-01-01" @default.
• W2076611240 modified "2023-10-17" @default.
• W2076611240 title "Direct pump/probe spectroscopy of the near-IR band of the solvated electron in alcohols" @default.
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• W2076611240 doi "https://doi.org/10.1016/0009-2614(94)01314-l" @default.
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