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- W2076614894 abstract "The application of thermodynamics in a rigorous way to pure and mixed insoluble surface films is considered. A Shuttleworth kind of treatment is developed and is compared with equivalent formalisms based on (i) the chemical potential of the film-forming substance at the surface and on (ii) a corresponding molar Helmholtz surface free energy. It is emphasized that complete thermodynamic studies of insoluble surface films must include measurements of equilibrium spreading properties and integration of each surface-pressure-molar-area isotherm." @default.
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- W2076614894 date "1971-12-01" @default.
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- W2076614894 title "Thermodynamics of surface-phase systems. VI. On the rigorous thermodynamics of insoluble surface films" @default.
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- W2076614894 doi "https://doi.org/10.1016/0021-9797(71)90344-4" @default.
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