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- W2076630944 abstract "Jadomycin B, an antifungal antibiotic with a unique 8H-benz[b]oxazolo[3,2-f]phenanthridine pentacyclic skeleton produced by the bacterium Streptomyces venezuelae ISP 5230, exists in a dynamic equilibrium of two diastereomers differing in the configuration of C-3a. Several novel jadomycins with various amino acid-derived 1-side chains could be generated, by replacing isoleucine in the production medium of S. venezuelae with other amino acids. These two findings led to the conclusion that a nonenzymatic reaction with the amino acid followed by a likewise nonenzymatic cyclization cascade are crucial for its late biosynthesis." @default.
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- W2076630944 date "2004-03-20" @default.
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- W2076630944 title "The Dynamic Structure of Jadomycin B and the Amino Acid Incorporation Step of Its Biosynthesis" @default.
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- W2076630944 doi "https://doi.org/10.1021/ja031724o" @default.
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