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• W2076658032 abstract "The conversion of the alkyne complex RhCl(PPr(i)3)2(eta2-PhC[triple bond]CH) into its vinylidene isomer RhCl(PPr(i)3)2(=C=CPhH) has been monitored via NMR spectroscopy in a range of solvents. In THF and hexane solution the reaction was observed to proceed via the alkynyl hydride complex Rh(H)Cl(PPr(i)3)2(-C[triple bond]CPh). The kinetic profile of the reaction demonstrates that this species is an intermediate in the formation of the vinylidene complex." @default.
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• W2076658032 date "2008-01-01" @default.
• W2076658032 modified "2023-09-23" @default.
• W2076658032 title "A mechanistic study into the interconversion of rhodium alkyne, alkynyl hydride and vinylidene complexes" @default.
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• W2076658032 doi "https://doi.org/10.1039/b806358c" @default.
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