FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076659094> ?p ?o ?g. }

• W2076659094 endingPage "45" @default.
• W2076659094 startingPage "37" @default.
• W2076659094 abstract "A series of 2,5-diferrocenyl-N-phenyl-1H-pyrroles of type 2,5-Fc2-cC4H2NPh (Fc = Fe(η5-C5H4)(η5-C5H4R); 3a, R = cC4H7O2; 3b, H; 3c, 3,5-(CF3)2-C6H3) was synthesized by Negishi C,C cross-coupling reactions to connect the heterocyclic unit with the redox active ferrocenyl moieties. The reaction of 3a with p-toluene sulfonic acid gave 3d (R = CHO). A subsequent cyanation reaction of 3d produced 3e (R = CN). Characterization of these molecules was performed by spectroscopic means and single crystal X-ray diffraction analysis (3c–e). It could be shown that the electronic properties of the 2,5-diferrocenyl-N-phenyl-1H-pyrroles is influenced by the substitution of electron withdrawing/donating functional groups in 1′-position of the ferrocenyls. The influence of the electronic nature of the substituents on the charge transfer character of the heterocyclic bridging system was investigated using electrochemical (cyclic and square-wave voltammetry) and spectroelectrochemical methodologies (in situ UV–Vis/NIR spectroscopy). The observed redox splittings ΔE°′ between the redox active ferrocenyls are 390 mV for 3a, 485 mV for 3c, 555 mV for 3d and 600 mV for 3e using [NnBu4][B(C6F5)4] as electrolyte. Furthermore, the electrochemistry studies were performed in [NnBu4][PF6] to determine changes of the electrostatic stabilization. The redox separation increases with increasing electron withdrawing ability of the ferrocenyl substituents in the order R = cC4H7O2 < H < 3,5-(CF3)2-C6H3 < CHO < CN, while the spectroelectrochemical studies reveal decreasing strength of the intramolecular electronic coupling between the iron atoms. All compounds show intense and broad absorptions in the NIR region and can be classified as strongly coupled class II systems according to Robin and Day." @default.
• W2076659094 created "2016-06-24" @default.
• W2076659094 creator A5000122909 @default.
• W2076659094 creator A5023056660 @default.
• W2076659094 creator A5039877065 @default.
• W2076659094 creator A5088536141 @default.
• W2076659094 date "2015-09-01" @default.
• W2076659094 modified "2023-09-25" @default.
• W2076659094 title "Electronic modification of redox active ferrocenyl termini and their influence on the electrontransfer properties of 2,5-diferrocenyl- N -phenyl-1 H -pyrroles" @default.
• W2076659094 cites W1967040140 @default.
• W2076659094 cites W1967411080 @default.
• W2076659094 cites W1968355139 @default.
• W2076659094 cites W1968564692 @default.
• W2076659094 cites W1969812510 @default.
• W2076659094 cites W1969820722 @default.
• W2076659094 cites W1979681359 @default.
• W2076659094 cites W1983709591 @default.
• W2076659094 cites W1984470045 @default.
• W2076659094 cites W1984830738 @default.
• W2076659094 cites W1990170643 @default.
• W2076659094 cites W1996247525 @default.
• W2076659094 cites W1997418114 @default.
• W2076659094 cites W1998863931 @default.
• W2076659094 cites W2006415222 @default.
• W2076659094 cites W2008861995 @default.
• W2076659094 cites W2009343463 @default.
• W2076659094 cites W2015505359 @default.
• W2076659094 cites W2022326124 @default.
• W2076659094 cites W2025498953 @default.
• W2076659094 cites W2027190895 @default.
• W2076659094 cites W2029039650 @default.
• W2076659094 cites W2031223934 @default.
• W2076659094 cites W2032657118 @default.
• W2076659094 cites W2034700558 @default.
• W2076659094 cites W2035317789 @default.
• W2076659094 cites W2040086103 @default.
• W2076659094 cites W2041953696 @default.
• W2076659094 cites W2042717087 @default.
• W2076659094 cites W2042799700 @default.
• W2076659094 cites W2045667962 @default.
• W2076659094 cites W2049225490 @default.
• W2076659094 cites W2049807213 @default.
• W2076659094 cites W2057820608 @default.
• W2076659094 cites W2062574576 @default.
• W2076659094 cites W2064590904 @default.
• W2076659094 cites W2066652663 @default.
• W2076659094 cites W2066932188 @default.
• W2076659094 cites W2069506896 @default.
• W2076659094 cites W2076339719 @default.
• W2076659094 cites W2076541829 @default.
• W2076659094 cites W2083566294 @default.
• W2076659094 cites W2088481620 @default.
• W2076659094 cites W2090443946 @default.
• W2076659094 cites W2103511628 @default.
• W2076659094 cites W2112969083 @default.
• W2076659094 cites W2128179591 @default.
• W2076659094 cites W213791877 @default.
• W2076659094 cites W2148066840 @default.
• W2076659094 cites W2153112259 @default.
• W2076659094 cites W2160706828 @default.
• W2076659094 cites W2160790360 @default.
• W2076659094 cites W2169474890 @default.
• W2076659094 cites W2170005578 @default.
• W2076659094 cites W2170909829 @default.
• W2076659094 cites W2312186160 @default.
• W2076659094 cites W2312331775 @default.
• W2076659094 cites W2316002875 @default.
• W2076659094 cites W2317669766 @default.
• W2076659094 cites W2318813498 @default.
• W2076659094 cites W2321142823 @default.
• W2076659094 cites W2324076324 @default.
• W2076659094 cites W2326173907 @default.
• W2076659094 cites W2328225160 @default.
• W2076659094 cites W2334384443 @default.
• W2076659094 cites W2497007159 @default.
• W2076659094 cites W2941905106 @default.
• W2076659094 cites W2949879655 @default.
• W2076659094 cites W2950108189 @default.
• W2076659094 cites W2951794262 @default.
• W2076659094 cites W2952312802 @default.
• W2076659094 cites W2952529360 @default.
• W2076659094 doi "https://doi.org/10.1016/j.jorganchem.2014.12.035" @default.
• W2076659094 hasPublicationYear "2015" @default.
• W2076659094 type Work @default.
• W2076659094 sameAs 2076659094 @default.
• W2076659094 citedByCount "29" @default.
• W2076659094 countsByYear W20766590942015 @default.
• W2076659094 countsByYear W20766590942016 @default.
• W2076659094 countsByYear W20766590942017 @default.
• W2076659094 countsByYear W20766590942018 @default.
• W2076659094 countsByYear W20766590942019 @default.
• W2076659094 countsByYear W20766590942020 @default.
• W2076659094 countsByYear W20766590942022 @default.
• W2076659094 countsByYear W20766590942023 @default.
• W2076659094 crossrefType "journal-article" @default.
• W2076659094 hasAuthorship W2076659094A5000122909 @default.
• W2076659094 hasAuthorship W2076659094A5023056660 @default.
• W2076659094 hasAuthorship W2076659094A5039877065 @default.

• next