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• W2076663721 abstract "A series of (benzimidazolylidene)pentacarbonylchromium(0) complexes were synthesized by the addition of lithium 1,2-phenylenediamides to Cr(CO)6 in the presence of 12-crown-4, followed by the treatment of chlorotrimethylsilane. X-ray crystal structural analysis revealed a rather single-bond-like character between Cr and the carbene carbon. One reversible oxidation process was observed in the cyclic voltammograms of these complexes. Chemical oxidation using (4-BrC6H4)3NSbCl6 was studied by ESR to afford a hyperfine structure derived not from Cr but from N and H, indicating that the spin is delocalized on the benzimidazolidene moiety." @default.
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• W2076663721 date "2005-03-01" @default.
• W2076663721 modified "2023-09-29" @default.
• W2076663721 title "Synthesis and oxidation of (benzimidazolylidene)Cr(CO)5 complexes" @default.
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• W2076663721 doi "https://doi.org/10.1016/j.jorganchem.2005.01.030" @default.
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