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- W2076673941 abstract "Abstract Experimental data on critical energy deficits of rare gas ions, protonated rare gases and proton donors, like ammonia or water are reported. Noble gas ions display appearance potentials which are correlated with their ionization potentials. Measurements on krypton showed that the appearance potentials of rare gas ions displayed no detectable field dependence. Thus, energy deficits are not influenced by polarization energies. The protonated rare gases XeH + , KrH + and ArH + can be measured on Rh-emitters during the field ionization of ammonia. Protonated rare gases display appearance potentials which are independent of their proton affinities. The appearance potentials of all protonated species are identical (10.3 ± 0.2 eV) and coincide with the value for NH 3 + (10.2 ± 0.1 eV). Protonation by water on a W-emitter gives results which are similar but not as distinct. The results are explained by a model with a fast proton-stripping mechanism, where proton transfer occurs without energy exchange at x c , the critical distance. It is the local potential at the point of formation, rather than the energetics of the process, which determines the critical energy loss of the field ions." @default.
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- W2076673941 date "1978-09-01" @default.
- W2076673941 modified "2023-09-27" @default.
- W2076673941 title "Critical energy deficits during the field ionization and proton capture of noble gases at rhodium and tungsten field emitters" @default.
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- W2076673941 doi "https://doi.org/10.1016/0020-7381(78)80068-0" @default.
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