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- W2076688995 abstract "A simple method has been developed for synthesis of carbons incorporating FeNx electrocatalysts (FeNC/C-z) based on heat treatment of nitrogen-rich species (pentaethylenehexamine) and iron precursors (FeCl3) on carbon blacks (Vulcan XC-72) under high temperature in a nitrogen atmosphere. These resulting catalysts have been fully characterized by various spectroscopic and analytical techniques such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS). Results obtained from the polarization curves show that FeNC/C-3.1 possesses the surpassing electrocatalytic activity and the tolerance to methanol crossover during the oxygen reduction reaction (ORR) among all the FeNC/C-z catalysts, which may be due to their higher surface Fe/C and N/C atomic ratios as well as a dominant carbon incorporated FeNx (x ≈ 4), as revealed from XPS and XAS spectroscopies." @default.
- W2076688995 created "2016-06-24" @default.
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- W2076688995 date "2014-03-01" @default.
- W2076688995 modified "2023-10-16" @default.
- W2076688995 title "Synthesis and characterization of carbon incorporated Fe–N/carbons for methanol-tolerant oxygen reduction reaction of polymer electrolyte fuel cells" @default.
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- W2076688995 doi "https://doi.org/10.1016/j.jpowsour.2013.11.011" @default.
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