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- W2076702949 abstract "Abstract Metal chelates of salicylaldoxime (H2BA) with titanium(IV), zirconium(IV) and hafnium(IV) have been investigated by the Bjerrum-Calvin pH-titration technique. Thermodynamic formation constants have been obtained by extrapolation of the values at various ionic concentrations. The ligand is biprotonic, the values of log K1 and log K2 (μ = 0) are 12·1 and 9·3. Titanium forms two chelates, the values of log K1 and log K2 (μ = 0) are 18·55 and 17·25 respectively. Zirconium and hafnium each form only a 1 : 1 chelate. The values of log K1 (μ = 0) are 17·9 and 16·7 respectively. The log Kμ=0 values for the ligand is 21·35 (exptl.), 21·40 (calc.) while those for the titanium, zirconium and hafnium chelates are respectively 35·60 (exptl.), 35·80 (calc.), 17·9 and 16·7 at 25°. The successive free energies (ΔF°) of the chelation reaction have also been evaluated." @default.
- W2076702949 created "2016-06-24" @default.
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- W2076702949 date "1968-06-01" @default.
- W2076702949 modified "2023-09-27" @default.
- W2076702949 title "Titanium(IV), zirconium(IV) and hafnium(IV) chelates of salicylaldoxime" @default.
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- W2076702949 doi "https://doi.org/10.1016/0022-1902(68)80548-2" @default.
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