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- W2076709713 abstract "Ethane hydrogenolysis on a Ru(1,1,10) stepped surface has been investigated by using a catalytic reactor cell linked to an UHV chamber. Reaction rates at steady state on the stepped surface are higher by one or two orders of magnitude than on supported catalysts. The reaction rates show kinetic orders of 0.55 and −0.75 with respect to the partial pressures of ethane and hydrogen, respectively, with an activation energy of 92 kJ/mol. The high activity of the Ru(1,1,10) surface is characterized with these smaller values of reaction orders and activation energy. Selective poisoning experiments using H2S indicate that the high activity can be ascribed to step sites having low-coordination-number surface atoms." @default.
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- W2076709713 date "1988-01-01" @default.
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- W2076709713 title "Ethane hydrogenolysis on a Ru(1,1,10) surface" @default.
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- W2076709713 doi "https://doi.org/10.1016/0039-6028(88)90465-7" @default.
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