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• W2076742282 abstract "Abstract A hydrothermal strategy combined with colloidal deposition synthesis was successfully used to grow ZnO/perovskite (LaBO 3 , B = Mn, Co, Ni) core–shell nanorod arrays within three dimensional (3-D) honeycomb cordierite substrates. A facile sonication assisted colloidal wash coating process is able to coat a uniformly dispersed perovskite nanoparticles onto the large scale ZnO nanorod arrays rooted on the channel surfaces of the 3D cordierite substrate achieved by hydrothermal synthesis. Compared to traditional wash-coated perovskite catalysts, an enhanced catalytic performance was observed for propane oxidation with 25 °C lower light-off temperature than powder-form coated perovskite catalyst of similar LaMnO 3 loading (4.3 mg). Temperature programmed reduction and desorption under H 2 and O 2 atmosphere, respectively, were used to study the reducibility and oxygen activity of these core–shell nanorod array based monolithic catalysts, revealing a catalytic activity sequence of LaCoO 3  > LaMnO 3  > La 2 NiO 4 at the initial stage of catalytic reaction. The good dispersion and size control in La-based perovskite nanoparticles and their interfaces to ZnO nanorod array support may contribute to the enhancement of catalytic performance. This work may provide a new type of Pt-group metals (PGM) free catalysts with improved catalytic performance for hydrocarbon oxidations at low temperature." @default.
• W2076742282 created "2016-06-24" @default.
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• W2076742282 date "2015-12-01" @default.
• W2076742282 modified "2023-10-12" @default.
• W2076742282 title "ZnO/perovskite core–shell nanorod array based monolithic catalysts with enhanced propane oxidation and material utilization efficiency at low temperature" @default.
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• W2076742282 doi "https://doi.org/10.1016/j.cattod.2015.03.026" @default.
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