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• W2076752135 abstract "Abstract Nano-sized Ni catalysts supported on MgO nano-rods were prepared by RF thermal plasma treatment of Ni metal (~ 5 μm) and MgO powders (~ 100 nm). For this purpose, each powder was ball-milled at pre-set molar ratio of 5:5, and then, injected into RF thermal plasma generated at the power level of ~ 25.5 kW. From FE-SEM (field emission scanning electron microscopy) and TEM-EDS (transmission electron microscopy-energy dispersive spectrometer) analyses, it is found that as-prepared catalysts mainly consist of very small Ni particles ( 4 :O 2  = 2:1 mol% with Ar diluents. Test results revealed that as-prepared MgO nano-rods supported Ni catalysts showed thermodynamic equilibrium values of methane conversion rate (> 99%) and high selectivity more than 90% and 80% for CO and H 2 at T = 750 °C, respectively. In spite of relatively high Ni content of 50 mol%, little carbon deposition is found in the TEM images and the derivative curves of TGA (thermogravimetry analysis) data for as-prepared catalysts after 24 h test at 750 °C, which are attributed to the structural features of Nano-sized Ni catalysts supported on MgO nano-rods prepared by RF thermal plasma." @default.
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• W2076752135 date "2013-08-01" @default.
• W2076752135 modified "2023-09-27" @default.
• W2076752135 title "Radio-frequency thermal plasma preparation of nano-sized Ni catalysts supported on MgO nano-rods for partial oxidation of methane" @default.
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• W2076752135 doi "https://doi.org/10.1016/j.surfcoat.2012.08.020" @default.
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