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• W2076755144 abstract "The rotational diffusion of charged colloidal boehmite needles in aqueous dispersions was assessed from the decay rate of optical birefringence after cessation of a shear flow. The strong dependence of the characteristic relaxation time τr on the ionic strength and the boehmite rod concentration can be described by a rescaling of the particle concentrations in terms of an “effective rotational volume” which takes the electric double layers into account. This dynamic rescaling is obeyed over a wide range of initial shear rates. Rotational relaxation times diverge when the effective particle concentration approaches the threshold density for the formation of a space-filling gel." @default.
• W2076755144 created "2016-06-24" @default.
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• W2076755144 date "1997-12-01" @default.
• W2076755144 modified "2023-10-14" @default.
• W2076755144 title "Decay of Flow Birefringence in Dispersions of Charged Colloidal Rods: Effect of Double-Layer Interactions" @default.
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• W2076755144 doi "https://doi.org/10.1021/la9708593" @default.
• W2076755144 hasPublicationYear "1997" @default.
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