Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076755964> ?p ?o ?g. }
- W2076755964 endingPage "164" @default.
- W2076755964 startingPage "155" @default.
- W2076755964 abstract "Anionic biological surfactant sodium cholate (NaC) and the zwitterionic nontoxic surfactant CHAPS (3-[(3-cholamidopropyl)dimethylammonio]-1-propanesulfonate) having common steroidal skeleton have not been studied in a comparative level to explore their amphiphilic behaviors separately and in mixed states. Their adsorption at the interface in relation to self-association in solution has been examined in both pure and mixed states with reference to detailed thermodynamic analysis of their surface chemical and solution behaviors. Their head group differences are responsible for the differences in their properties viz. critical micelle concentration (CMC), aggregation number (N), hydrodynamic diameter, Gibbs surface excess (Γmax), minimum head group area (Amin), mixed micelle composition and their mixing ideality/nonideality. Although the CMC values found from tensiometry and isothermal titration calorimetry (ITC) are in good agreement, the standard enthalpy of micellization (ΔHm(0)) found from ITC at different temperatures are different from that evaluated by the van't Hoff method. This is because van't Hoff rationale is a differential method which estimates the enthalpy of the monomer ↔ micelle equilibrium process whereas calorimetry is an integral process that evaluates all probable/possible processes in addition to monomer to micelle conversion. Results are analyzed, compared and discussed in the light of physicochemical parameters of pure NaC and CHAPS and their mixtures. These fundamental findings are considered prospective in pharmaceutical, biochemical and biomedical applications of the studied bio-friendly amphiphiles." @default.
- W2076755964 created "2016-06-24" @default.
- W2076755964 creator A5009235974 @default.
- W2076755964 creator A5050261884 @default.
- W2076755964 creator A5058998689 @default.
- W2076755964 date "2013-12-01" @default.
- W2076755964 modified "2023-10-06" @default.
- W2076755964 title "Amphiphilic activities of anionic sodium cholate (NaC), zwitterionic 3-[(3-cholamidopropyl)dimethylammonio]-1-propanesulfonate (CHAPS) and their mixtures: A comparative study" @default.
- W2076755964 cites W1533933224 @default.
- W2076755964 cites W194708975 @default.
- W2076755964 cites W1970944981 @default.
- W2076755964 cites W1975224651 @default.
- W2076755964 cites W1975689359 @default.
- W2076755964 cites W1977461924 @default.
- W2076755964 cites W1978267212 @default.
- W2076755964 cites W1978935243 @default.
- W2076755964 cites W1979753067 @default.
- W2076755964 cites W1984643020 @default.
- W2076755964 cites W1986913927 @default.
- W2076755964 cites W1994003100 @default.
- W2076755964 cites W1996827534 @default.
- W2076755964 cites W2006102863 @default.
- W2076755964 cites W2006461924 @default.
- W2076755964 cites W2007694386 @default.
- W2076755964 cites W2011876351 @default.
- W2076755964 cites W2012017553 @default.
- W2076755964 cites W2015256465 @default.
- W2076755964 cites W2015725057 @default.
- W2076755964 cites W2018442431 @default.
- W2076755964 cites W2024069103 @default.
- W2076755964 cites W2024633627 @default.
- W2076755964 cites W2025561938 @default.
- W2076755964 cites W2025928881 @default.
- W2076755964 cites W2026050496 @default.
- W2076755964 cites W2029459167 @default.
- W2076755964 cites W2034611491 @default.
- W2076755964 cites W2035640036 @default.
- W2076755964 cites W2036893362 @default.
- W2076755964 cites W2038825849 @default.
- W2076755964 cites W2042353996 @default.
- W2076755964 cites W2044359933 @default.
- W2076755964 cites W2047433495 @default.
- W2076755964 cites W2049892657 @default.
- W2076755964 cites W2050695348 @default.
- W2076755964 cites W2052864501 @default.
- W2076755964 cites W2054351670 @default.
- W2076755964 cites W2055361249 @default.
- W2076755964 cites W2059560778 @default.
- W2076755964 cites W2061770830 @default.
- W2076755964 cites W2062292386 @default.
- W2076755964 cites W2067738797 @default.
- W2076755964 cites W2068575822 @default.
- W2076755964 cites W2073421855 @default.
- W2076755964 cites W2073903657 @default.
- W2076755964 cites W2081264168 @default.
- W2076755964 cites W2082650875 @default.
- W2076755964 cites W2085872857 @default.
- W2076755964 cites W2087111913 @default.
- W2076755964 cites W2089137287 @default.
- W2076755964 cites W2090119786 @default.
- W2076755964 cites W2093694034 @default.
- W2076755964 cites W2099833838 @default.
- W2076755964 cites W2137451156 @default.
- W2076755964 cites W2164568406 @default.
- W2076755964 cites W2165007501 @default.
- W2076755964 cites W2167560618 @default.
- W2076755964 cites W2315356493 @default.
- W2076755964 cites W2319093870 @default.
- W2076755964 cites W2321785518 @default.
- W2076755964 cites W2323327750 @default.
- W2076755964 cites W2329159313 @default.
- W2076755964 doi "https://doi.org/10.1016/j.colsurfb.2013.07.029" @default.
- W2076755964 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23973673" @default.
- W2076755964 hasPublicationYear "2013" @default.
- W2076755964 type Work @default.
- W2076755964 sameAs 2076755964 @default.
- W2076755964 citedByCount "24" @default.
- W2076755964 countsByYear W20767559642014 @default.
- W2076755964 countsByYear W20767559642015 @default.
- W2076755964 countsByYear W20767559642016 @default.
- W2076755964 countsByYear W20767559642018 @default.
- W2076755964 countsByYear W20767559642019 @default.
- W2076755964 countsByYear W20767559642020 @default.
- W2076755964 countsByYear W20767559642021 @default.
- W2076755964 countsByYear W20767559642022 @default.
- W2076755964 countsByYear W20767559642023 @default.
- W2076755964 crossrefType "journal-article" @default.
- W2076755964 hasAuthorship W2076755964A5009235974 @default.
- W2076755964 hasAuthorship W2076755964A5050261884 @default.
- W2076755964 hasAuthorship W2076755964A5058998689 @default.
- W2076755964 hasConcept C11268172 @default.
- W2076755964 hasConcept C121332964 @default.
- W2076755964 hasConcept C147789679 @default.
- W2076755964 hasConcept C156911925 @default.
- W2076755964 hasConcept C15920480 @default.
- W2076755964 hasConcept C178790620 @default.
- W2076755964 hasConcept C181199279 @default.
- W2076755964 hasConcept C184651966 @default.