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- W2076759964 abstract "[Co4(μ4-SiMe)2(CO)11] (1a) is the major product from the reaction of [CO2(CO)8] with [Fe(SiMeH2)2(CO)4] (synthesised from SiMeH2Cl and Na2[Fe(CO)4]). An alternative, quantitative synthesis of 1a is from SiMeH3 and [Co4(CO) 12]. 1a reacts with an equimolar amount of GeMe2H2 to form in high yield [Co4(μ4-SiMe)2(μ-GeMe2(CO)10] (2), in which the μ-GeMe2 group has replaced the bridging carbonyl of the parent compound. Molecular structures were determined for 1a and 2." @default.
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- W2076759964 date "1993-02-01" @default.
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- W2076759964 title "Synthesis of the square-bipyramidal cluster [Co4(μ4-SiMe)2(CO)11] by two routes and its reaction with GeMe2H2. The crystal structures of [CO4(μ4-SiMe)2(CO)11] and [CO4(μ4-SiMe)2 μ-GeMe2(CO)10]" @default.
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- W2076759964 doi "https://doi.org/10.1016/0022-328x(93)83076-8" @default.
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