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- W2076773685 abstract "Three new phosphonoacetate hybrid frameworks based on the actinide elements uranium and thorium have been synthesized. The compounds [C(4)N(2)H(14)][(UO(2))(2)(O(3)PCH(2)COO)(2)] x H(2)O, I, [C(4)N(2)H(14)][(UO(2))(2)(C(2)O(4))(O(3)PCH(2)COOH)(2)], II, and Th(H(2)O)(2)(O(3)PCH(2)COO)(C(2)O(4))(0.5) x H(2)O, III, are built up from the connectivity between the metal polyhedra and the phosphonoacetate/oxalate units. Compound II has been prepared using a solvent-free approach, by a solid state reaction at 150 degrees C. It has been shown that II can also be prepared through a room temperature mechanochemical (grinding) route. The layer arrangement in III closely resembles to that observed in I. The compounds have been characterized by powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and fluorescence studies." @default.
- W2076773685 created "2016-06-24" @default.
- W2076773685 creator A5010877741 @default.
- W2076773685 creator A5025819073 @default.
- W2076773685 creator A5078034060 @default.
- W2076773685 date "2010-07-27" @default.
- W2076773685 modified "2023-10-09" @default.
- W2076773685 title "Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium" @default.
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- W2076773685 doi "https://doi.org/10.1021/ic101043z" @default.
- W2076773685 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20799739" @default.
- W2076773685 hasPublicationYear "2010" @default.
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