Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076789081> ?p ?o ?g. }
- W2076789081 endingPage "1474" @default.
- W2076789081 startingPage "1457" @default.
- W2076789081 abstract "The role of molecular rotations in the exchange of vibrational and translational energy is investigated for collisions between anharmonic diatomic molecules and structureless atoms. A three-dimensional, semiclassical, impact parameter description is applied with emphasis directed towards the influence of rotational coupling on the net rate of vibrational energy transfer summed over all final rotational states. These results are then related to the predictions of an equivalent collinear collision model, and their comparison allows an evaluation of the collinear approximation. The mechanisms of vibrational energy transfer including rotational transitions are shown to be separable into three classes, with the molecules belonging to each class identified first and foremost by their ratio of fundamental vibrational and rotational frequencies, ωe/Be, and second by the proximity of their initial state to a near-resonant vibration–rotation transition with a small change in angular momentum. While the dynamics of molecules with ωe/Be ratios that are comparable to the range of angular momentum transitions having strong coupling are found to require a complete three-dimensional description, the rates of vibrational energy transfer in molecules with large ωe/Be ratios appear to be well approximated by a collinear collision model." @default.
- W2076789081 created "2016-06-24" @default.
- W2076789081 creator A5077100093 @default.
- W2076789081 date "1977-02-15" @default.
- W2076789081 modified "2023-10-16" @default.
- W2076789081 title "The influence of molecular rotation on vibration–translation energy transfer" @default.
- W2076789081 cites W1963744362 @default.
- W2076789081 cites W1964353622 @default.
- W2076789081 cites W1964738742 @default.
- W2076789081 cites W1972119647 @default.
- W2076789081 cites W1978021727 @default.
- W2076789081 cites W1981196482 @default.
- W2076789081 cites W1982782993 @default.
- W2076789081 cites W1983318866 @default.
- W2076789081 cites W2011337717 @default.
- W2076789081 cites W2011616785 @default.
- W2076789081 cites W2020328455 @default.
- W2076789081 cites W2023594453 @default.
- W2076789081 cites W2028327467 @default.
- W2076789081 cites W2031946533 @default.
- W2076789081 cites W2034573741 @default.
- W2076789081 cites W2036281255 @default.
- W2076789081 cites W2047303023 @default.
- W2076789081 cites W2048972702 @default.
- W2076789081 cites W2049581332 @default.
- W2076789081 cites W2050489854 @default.
- W2076789081 cites W2050941235 @default.
- W2076789081 cites W2052493048 @default.
- W2076789081 cites W2056562103 @default.
- W2076789081 cites W2059814448 @default.
- W2076789081 cites W2064761328 @default.
- W2076789081 cites W2068405606 @default.
- W2076789081 cites W2070276993 @default.
- W2076789081 cites W2071864420 @default.
- W2076789081 cites W2074042446 @default.
- W2076789081 cites W2086336282 @default.
- W2076789081 cites W2087569397 @default.
- W2076789081 cites W2093026413 @default.
- W2076789081 cites W2093267681 @default.
- W2076789081 cites W2093604024 @default.
- W2076789081 cites W2095137080 @default.
- W2076789081 cites W2110788816 @default.
- W2076789081 cites W2128192329 @default.
- W2076789081 cites W2150157568 @default.
- W2076789081 cites W2153463401 @default.
- W2076789081 cites W2157927958 @default.
- W2076789081 cites W2160872510 @default.
- W2076789081 cites W2021675531 @default.
- W2076789081 doi "https://doi.org/10.1063/1.434108" @default.
- W2076789081 hasPublicationYear "1977" @default.
- W2076789081 type Work @default.
- W2076789081 sameAs 2076789081 @default.
- W2076789081 citedByCount "23" @default.
- W2076789081 crossrefType "journal-article" @default.
- W2076789081 hasAuthorship W2076789081A5077100093 @default.
- W2076789081 hasConcept C111167017 @default.
- W2076789081 hasConcept C111806078 @default.
- W2076789081 hasConcept C121332964 @default.
- W2076789081 hasConcept C121704057 @default.
- W2076789081 hasConcept C131584629 @default.
- W2076789081 hasConcept C147724859 @default.
- W2076789081 hasConcept C155675718 @default.
- W2076789081 hasConcept C169146920 @default.
- W2076789081 hasConcept C181500209 @default.
- W2076789081 hasConcept C184779094 @default.
- W2076789081 hasConcept C185592680 @default.
- W2076789081 hasConcept C191486275 @default.
- W2076789081 hasConcept C191897082 @default.
- W2076789081 hasConcept C192562407 @default.
- W2076789081 hasConcept C198394728 @default.
- W2076789081 hasConcept C24123453 @default.
- W2076789081 hasConcept C2524010 @default.
- W2076789081 hasConcept C2993504562 @default.
- W2076789081 hasConcept C32909587 @default.
- W2076789081 hasConcept C33923547 @default.
- W2076789081 hasConcept C38652104 @default.
- W2076789081 hasConcept C41008148 @default.
- W2076789081 hasConcept C45193367 @default.
- W2076789081 hasConcept C535169671 @default.
- W2076789081 hasConcept C62520636 @default.
- W2076789081 hasConcept C74050887 @default.
- W2076789081 hasConcept C76494280 @default.
- W2076789081 hasConcept C84114770 @default.
- W2076789081 hasConceptScore W2076789081C111167017 @default.
- W2076789081 hasConceptScore W2076789081C111806078 @default.
- W2076789081 hasConceptScore W2076789081C121332964 @default.
- W2076789081 hasConceptScore W2076789081C121704057 @default.
- W2076789081 hasConceptScore W2076789081C131584629 @default.
- W2076789081 hasConceptScore W2076789081C147724859 @default.
- W2076789081 hasConceptScore W2076789081C155675718 @default.
- W2076789081 hasConceptScore W2076789081C169146920 @default.
- W2076789081 hasConceptScore W2076789081C181500209 @default.
- W2076789081 hasConceptScore W2076789081C184779094 @default.
- W2076789081 hasConceptScore W2076789081C185592680 @default.
- W2076789081 hasConceptScore W2076789081C191486275 @default.
- W2076789081 hasConceptScore W2076789081C191897082 @default.
- W2076789081 hasConceptScore W2076789081C192562407 @default.
- W2076789081 hasConceptScore W2076789081C198394728 @default.