Matches in SemOpenAlex for { <https://semopenalex.org/work/W2076790168> ?p ?o ?g. }
- W2076790168 endingPage "229" @default.
- W2076790168 startingPage "221" @default.
- W2076790168 abstract "A large number of SnX4·2L and SnX4·L-L tin(IV) tetrahalide adducts were synthesized and analyzed (X = Cl, Br; L = Me2O, Et2O, THF, Me2S, Et2S, THT, Me2Se, MeCN, Me3CCN, Me3CO, HMPA, TMPA; L−L = (MeOCH2−)2). Their cis or trans geometry was determined by infrared and Raman spectroscopy. For the SnCl4·2THT adduct, both isomers could be isolated by changing the solvent polarity. The existence of a cis-trans equilibrium in solution has been demonstrated for the majority of the adducts by Raman measurements. This equilibrium strongly depends upon the solvent polarity, the cis isomer being favoured in a highly polar medium. Using a simplified model for Wilson's FG matrices, the Sn-X force constants were determined and the following sequences deduced for the strength of the tin-ligand bond in SnX4·2L: Me2Se > Me2S ∼ THT ∼ Et2S > Me2O ∼ THF ∼ Et2O and HMPA > TMPA." @default.
- W2076790168 created "2016-06-24" @default.
- W2076790168 creator A5004194022 @default.
- W2076790168 creator A5055599135 @default.
- W2076790168 date "1976-01-01" @default.
- W2076790168 modified "2023-09-27" @default.
- W2076790168 title "Adducts of tin(IV) tetrahalides with neutral lewis bases. I. Vibrational study of the cis-trans isomerism in solution" @default.
- W2076790168 cites W1590482039 @default.
- W2076790168 cites W1982152302 @default.
- W2076790168 cites W1988442826 @default.
- W2076790168 cites W1988482084 @default.
- W2076790168 cites W1996666937 @default.
- W2076790168 cites W2009065803 @default.
- W2076790168 cites W2010909424 @default.
- W2076790168 cites W2015701999 @default.
- W2076790168 cites W2039866607 @default.
- W2076790168 cites W2046671948 @default.
- W2076790168 cites W2064927892 @default.
- W2076790168 cites W2093626830 @default.
- W2076790168 cites W2140139359 @default.
- W2076790168 cites W2314753623 @default.
- W2076790168 cites W2322558389 @default.
- W2076790168 doi "https://doi.org/10.1016/s0020-1693(00)94120-3" @default.
- W2076790168 hasPublicationYear "1976" @default.
- W2076790168 type Work @default.
- W2076790168 sameAs 2076790168 @default.
- W2076790168 citedByCount "67" @default.
- W2076790168 countsByYear W20767901682012 @default.
- W2076790168 countsByYear W20767901682013 @default.
- W2076790168 countsByYear W20767901682014 @default.
- W2076790168 countsByYear W20767901682017 @default.
- W2076790168 countsByYear W20767901682018 @default.
- W2076790168 countsByYear W20767901682022 @default.
- W2076790168 crossrefType "journal-article" @default.
- W2076790168 hasAuthorship W2076790168A5004194022 @default.
- W2076790168 hasAuthorship W2076790168A5055599135 @default.
- W2076790168 hasConcept C10710636 @default.
- W2076790168 hasConcept C108204754 @default.
- W2076790168 hasConcept C116569031 @default.
- W2076790168 hasConcept C120665830 @default.
- W2076790168 hasConcept C121332964 @default.
- W2076790168 hasConcept C1276947 @default.
- W2076790168 hasConcept C147789679 @default.
- W2076790168 hasConcept C1491633281 @default.
- W2076790168 hasConcept C153642686 @default.
- W2076790168 hasConcept C155647269 @default.
- W2076790168 hasConcept C158355884 @default.
- W2076790168 hasConcept C161790260 @default.
- W2076790168 hasConcept C163638829 @default.
- W2076790168 hasConcept C170493617 @default.
- W2076790168 hasConcept C176788430 @default.
- W2076790168 hasConcept C178790620 @default.
- W2076790168 hasConcept C185592680 @default.
- W2076790168 hasConcept C2777361361 @default.
- W2076790168 hasConcept C2780471494 @default.
- W2076790168 hasConcept C29705727 @default.
- W2076790168 hasConcept C2992176605 @default.
- W2076790168 hasConcept C40003534 @default.
- W2076790168 hasConcept C525849907 @default.
- W2076790168 hasConcept C55493867 @default.
- W2076790168 hasConcept C71240020 @default.
- W2076790168 hasConceptScore W2076790168C10710636 @default.
- W2076790168 hasConceptScore W2076790168C108204754 @default.
- W2076790168 hasConceptScore W2076790168C116569031 @default.
- W2076790168 hasConceptScore W2076790168C120665830 @default.
- W2076790168 hasConceptScore W2076790168C121332964 @default.
- W2076790168 hasConceptScore W2076790168C1276947 @default.
- W2076790168 hasConceptScore W2076790168C147789679 @default.
- W2076790168 hasConceptScore W2076790168C1491633281 @default.
- W2076790168 hasConceptScore W2076790168C153642686 @default.
- W2076790168 hasConceptScore W2076790168C155647269 @default.
- W2076790168 hasConceptScore W2076790168C158355884 @default.
- W2076790168 hasConceptScore W2076790168C161790260 @default.
- W2076790168 hasConceptScore W2076790168C163638829 @default.
- W2076790168 hasConceptScore W2076790168C170493617 @default.
- W2076790168 hasConceptScore W2076790168C176788430 @default.
- W2076790168 hasConceptScore W2076790168C178790620 @default.
- W2076790168 hasConceptScore W2076790168C185592680 @default.
- W2076790168 hasConceptScore W2076790168C2777361361 @default.
- W2076790168 hasConceptScore W2076790168C2780471494 @default.
- W2076790168 hasConceptScore W2076790168C29705727 @default.
- W2076790168 hasConceptScore W2076790168C2992176605 @default.
- W2076790168 hasConceptScore W2076790168C40003534 @default.
- W2076790168 hasConceptScore W2076790168C525849907 @default.
- W2076790168 hasConceptScore W2076790168C55493867 @default.
- W2076790168 hasConceptScore W2076790168C71240020 @default.
- W2076790168 hasLocation W20767901681 @default.
- W2076790168 hasOpenAccess W2076790168 @default.
- W2076790168 hasPrimaryLocation W20767901681 @default.
- W2076790168 hasRelatedWork W2001552383 @default.
- W2076790168 hasRelatedWork W2006089966 @default.
- W2076790168 hasRelatedWork W2011590048 @default.
- W2076790168 hasRelatedWork W2016371902 @default.
- W2076790168 hasRelatedWork W2030783701 @default.
- W2076790168 hasRelatedWork W2086710427 @default.
- W2076790168 hasRelatedWork W2110606576 @default.
- W2076790168 hasRelatedWork W2151944362 @default.
- W2076790168 hasRelatedWork W3015045800 @default.