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- W2076795622 abstract "Methoxycarbonyl-protected methallyl amine serves as an excellent substrate for chloroperoxidase-mediated asymmetric epoxidation. The resulting (R)-epoxide (94% ee) was converted to the title compound in three steps with nearly complete maintenance of stereochemical integrity. Titanium tetrachloride ring-opening of the epoxide provided the chlorohydrin with excellent selectivity and inversion of the stereogenic center. Oxidation with pyridinium dichromate was followed by ring-closure to the aziridine which was esterified in situ with methyl iodide." @default.
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- W2076795622 date "1997-11-01" @default.
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- W2076795622 title "Chloroperoxidase-mediated asymmetric epoxidation. Synthesis of (R)-dimethyl 2-methylaziridine-1,2-dicarboxylate—a potential α-methylamino acid synthon" @default.
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- W2076795622 doi "https://doi.org/10.1016/s0957-4166(97)00467-9" @default.
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