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- W2076802911 abstract "Abstract The reactions of the chiral 2- p -tolylsulfinyl cyclohexanols with Ac 2 O/NaOAc (or (CF 3 CO) 2 O/Py) at r.t. yielded the 2- p -tolylsulfenyl-2-cyclohexenyl acetates, which cannot be hydrolyzed into the α-hydroxyketones. The 1-methyl-2- p -tolylsulfinylcyclohexanols evolved with (CF 3 CO) 2 O/Py into the 3-methyl-2- p -tolylsulfenyl-2-cyclohexenyl trifluoroacetates, the latter resulting from a very highly stereoselective hetero-Claisen rearrangement (e.e.97%) of the initially formed 1-methyl-2- p -tolylsulfenyl-2-cyclohexenyl trifluoroacetates." @default.
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- W2076802911 date "1992-01-01" @default.
- W2076802911 modified "2023-10-03" @default.
- W2076802911 title "Behaviour of 2-p-tolylsulfinyl cyclohexanols under the pummerer reaction conditions" @default.
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- W2076802911 doi "https://doi.org/10.1016/s0957-4166(00)80203-7" @default.
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