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- W2076818085 abstract "Oxidation of n-butane was investigated on vanadyl phosphate (VP) prepared in the presence of titania (anatase) and silica as supports. In the case of silica, α-VOPO 4 was synthesized with no sign of interaction between the silica surface and vanadium phosphate. On the contrary, titania was coated with amorphous VP (P/V = 1), preventing the crystallization of VOPO 4 at least up to the VP content of 21%. n-Butane was completely converted into CO 2 for the VP/TiO 2 catalytic system. Upon impregnation with metal sulfates, maleic anhydride (MA) was produced with selectivities depending on the nature of the added metallic species, the best effect being observed with Fe 2+ (V/Fe = 3). Selectivities to MA were influenced by the P/V ratio, with a maximum at P/V = 1.2. Keywords: vanadyl phosphate, maleic anhydride, butane oxidation, anatase, rutile." @default.
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- W2076818085 date "1992-01-01" @default.
- W2076818085 modified "2023-10-18" @default.
- W2076818085 title "Catalytic activity of vanadyl phosphate supported on TiO2 (anatase) and SiO2 (silica)" @default.
- W2076818085 doi "https://doi.org/10.1139/v92-002" @default.
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