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- W2076844101 abstract "In the reaction of C 5 H 5 Mo(CO) 3 Cl with ethylenediamine and propylenediamine, abbreviated with NN′, the square pyramidal cations [C 5 H 5 Mo(CO) 2 NN′] + are formed. The diastereoisomeric pairs of enantiomers of the propylenediamine derivative are separated by fractional crystallization. The epimerization at the asymmetric Mo atom (τ 1,2 = 30 min, 75 °C, CD 3 OD solution) can be followed by 1 H NMR spectroscopy" @default.
- W2076844101 created "2016-06-24" @default.
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- W2076844101 date "1978-02-01" @default.
- W2076844101 modified "2023-09-27" @default.
- W2076844101 title "Optisch aktive Übergangsmetall-Komplexe, LV [1]. Darstellung und Stereochemie von [C<sub>5</sub>H<sub>5</sub>Mo(CO)<sub>2</sub> NN’]PF<sub>6</sub> mit NN’=Ethylen-diamin und Propylendiamin / Optically Active Transition Metal Complexes, LV [1]. Preparation und Stereochemistry of [C<sub>5</sub>H<sub>5</sub>Mo(CO)<sub>2</sub>NN′]PF<sub>6</sub> with NN′=Ethylenediamine and Propylene- diamine" @default.
- W2076844101 doi "https://doi.org/10.1515/znb-1978-0230" @default.
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