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- W2076885510 abstract "Treatment of resibufogenin (1a) or its acetate (1b) with perchloric acid or hydrochloric acid gave 14α-and 14β-artebufogenin (5a and 6a, or 5b and 6b), in addition to 15α-hydroxy-bufalin (4a or b). Reaction of epoxide 1b with chloranil or boron trifluoride etherate easily afforded 14α- and 14β-artebufogenin acetate (5b and 6b) in good yields. Analogous reaction of the isomeric 3β-hydroxy-14α,15α-epoxide 3a with perchloric acid, hydrochloric acid, or sulfuric acid again led to 14α- and 14β-artebufogenin (5a and 6a) and the 14β,15α-dihydroxy-derivative 4a, Similar reaction with periodic acid gave 6a and 4a." @default.
- W2076885510 created "2016-06-24" @default.
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- W2076885510 date "1973-06-15" @default.
- W2076885510 modified "2023-10-16" @default.
- W2076885510 title "Bufadienolides. 17. Synthesis of 14α- and 14β-Artebufogenin" @default.
- W2076885510 doi "https://doi.org/10.1139/v73-295" @default.
- W2076885510 hasPublicationYear "1973" @default.
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