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• W2076914955 endingPage "267" @default.
• W2076914955 startingPage "263" @default.
• W2076914955 abstract "A new c]ass of mixed ligand complexes, of copper(I) hexamethyleneimine-2-thione (ω-thiocaprolactam, tclH) with triphenylphosphine and triphenylarsine is synthesized and characterized. The complexes may be formulated as [Cu(tclH)2(EPh3)X], where E= P or As; X = Cl, Br or I. The arsine complexes express a remarkable photostability compared to their phosphine counterparts. Moreover, they do not react with stoichiometric amounts of pyridine which, in the case of the phosphine complexes displaces the thione ligands coordinated to copper. Furthermore, the crystal structure of the complex [Cu(tclH)2(AsPh3)Br], which is also discussed is the first one to present a mixed ligand arsine-thione copper(I) complex. The compound crystallizes in the P21/n space group, with a = 18.704(1), b = 10.855(1), c = 15.593(1) Å and β = 92.70(1)°. A distorted tetrahedral environment around copper is present, with the two CuS bonds almost equivalent (2.310(1) and 2.315(1) Å). The CuAs bond distance is equal to 23711 Å and the CuBr bond length is 2605(1) Å." @default.
• W2076914955 created "2016-06-24" @default.
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• W2076914955 date "1991-03-01" @default.
• W2076914955 modified "2023-10-18" @default.
• W2076914955 title "New class of Cu(I) complexes with 2-thioxohexamethyleneimine (tclH) and Group VA donors. Crystal structure of [Cu(tclH)2(AsPh3)Br]" @default.
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• W2076914955 doi "https://doi.org/10.1016/s0020-1693(00)86819-x" @default.
• W2076914955 hasPublicationYear "1991" @default.
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