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- W2076939599 abstract "Abstract The anisotropy of the diamagnetic susceptibility of the smectic liquid crystal p,p'-di-nheptylazoxybenzene (HAB) has been measured by use of 1H NMR. The value of (X‖ - X⊥) is found as e.g. 1.418. 10−6 at 318 K. Furthermore, we have observed local solvent effects of HAB on dissolved globular molecules, which are of the order of 0.10 to 0.19 ppm for methane, 0.37 to 0.44 ppm for tetramethylsilane, 0.35 to 0.40 ppm for tetramethylstannane, and 0.39 to 0.41 ppm for neopentane. These values are dependent on temperature and may lead to large uncertainties in the determination of proton chemical shift anisotropics. A theoretical treatment of the magnetic fields in the annulus of a double-wall tube and inside the inner tube filled with a smectic liquid crystal and variable angle between the applied field and the optic axis is also given." @default.
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- W2076939599 date "1982-01-01" @default.
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- W2076939599 title "The Smectic Phase ofp. p'-di-n-Heptylazoybenzene: A1H NMR study of Its Anisotropy of Diamagnetic Susceptibility and of Its Use for Measuring Proton Chemical Shift Anisotropies" @default.
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- W2076939599 doi "https://doi.org/10.1080/00268948208084450" @default.
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