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- W2076953651 abstract "Coverage by adsorbed intermediates formed by charge transfer depends on potential as a result of two physically independent phenomena. On the one hand the charge transfer process at (quasi) equilibrium leads to a Nernst type equation, in which empty sites on the surface are considered as reactants and adsorbed intermediates are considered as the product. On the other hand, competition with water gives rise to a potential dependence of adsorption of neutral species. The combined adsorption isotherm developed by the present author combines these two effects for a more accurate description of adsorption of intermediates formed by charge transfer, which displace a significant number of water molecules from the surface. The application of the combined isotherm to equilibrium situations and its effect on the calculated adsorption pseudocapacity are discussed. The effect of the size of the adsorbed intermediate on the Tafel slope is derived. Experimental evidence showing a gradual change in the Tafel slope for a series of nitroalkanes is given, and the mechanism which has been derived for this case is described. It is concluded that the size of adsorbed intermediates has an influence on the observed Tafel slope. The effects expected are relatively small (b = 53, 58 and 62 mV for nitromethane, nitroethane and isonitropropane, respectively) and require very accurate measurements of the Tafel slope." @default.
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- W2076953651 date "1987-02-01" @default.
- W2076953651 modified "2023-09-27" @default.
- W2076953651 title "The combined adsorption isotherm" @default.
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- W2076953651 doi "https://doi.org/10.1016/0013-4686(87)85028-4" @default.
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