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- W2076977037 abstract "Four new coordination polymers (CPs), {[Zn2(L)4]·7H2O}n (1), {[Zn2(L)4]·4H2O}n (2), {[Zn(L)2]·3/2H2O}n (3) and {[Cd(L)2]·3H2O}n (4) (HL = 4-benzoimidazol-1-yl-methyl benzoic acid) have been synthesized under hydrothermal conditions. All the complexes have been characterized by single crystal X-ray crystallography (XRD), IR spectroscopy, elemental analysis and thermogravimetry (TGA). Complexes 1–4 show similar 2D, non-interpenetrated, uninodal 4-connected layers that are further connected by H-bonding interactions to 3D supramolecular structures. For the complexes 1–3, the overall architecture is controlled by the template used. All complexes exhibit high thermal stability losing coordinated water molecules at ∼110 °C. Upon excitation at 343 nm, compounds 1–3 exhibit solid-state luminescence at room temperature. The intensity of luminescence gradually decreases with an increase in the number of lattice water molecules per Zn(II) center due to vibrational quenching by water molecules." @default.
- W2076977037 created "2016-06-24" @default.
- W2076977037 creator A5019478816 @default.
- W2076977037 creator A5087260159 @default.
- W2076977037 date "2013-03-01" @default.
- W2076977037 modified "2023-10-17" @default.
- W2076977037 title "Synthesis of coordination polymers with d10 metal ions and a new linear ligand: X-ray structural and luminescence studies" @default.
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- W2076977037 doi "https://doi.org/10.1016/j.poly.2012.06.055" @default.
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