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- W2077019076 abstract "Abstract New experimental phase equilibrium data on the system supercritical CO 2 –lemon oil are provided at 50 °C and 70 °C, for pressures in the range 8.6–10.1 MPa and 9.7–13.5 MPa, respectively. Additional phase equilibrium data on the binary sub-system CO 2 –limonene are also provided. The measurements were carried out in a double-chamber isothermal apparatus of 340 cm 3 . Both the mass fraction of CO 2 in the two phases and in the overall system was measured. The composition of the two phases on CO 2 -free basis was also measured. A thermodynamic model based on the Peng–Robinson equation of state was developed in order to represent the behaviour of the system supercritical CO 2 –lemon oil. The model uses only regression parameters calculated from binary sub-systems, thus being predictive with respect to the multicomponent mixture. A good representation of the phase equilibrium data is obtained with the proposed thermodynamic model." @default.
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- W2077019076 date "2012-10-01" @default.
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- W2077019076 title "Phase equilibrium of the system supercritical carbon dioxide–lemon essential oil: New experimental data and thermodynamic modelling" @default.
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- W2077019076 doi "https://doi.org/10.1016/j.supflu.2012.06.003" @default.
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