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- W2077055537 abstract "Atom transfer radical polymerization (ATRP) using a norbornenyl-functionalized initiator was established as a new synthetic method for the preparation of macromolecules that are both α-norbornenyl macromonomers and ω-haloalkyl macroinitiators. When styrene, methyl methacrylate, and tert-butyl methacrylate were used as monomer or constituted comonomer pairs, the (co)polymerization was well-controlled and the norbornenyl functionality was intact. The resulting homopolymer or statistical copolymer-based macromonomers had linear structures, quantitative α-norbornenyl functionality, controlled number-average molecular weights (Mn = 3600−24300 Da), and narrow monomodal molecular weight distributions (Mw/Mn = 1.07−1.35). Their ω-halide terminals further allowed them to serve as macroinitiators for the syntheses of block copolymer-based α-norbornenyl macromonomers by ATRP. In contrast, the norbornenyl functionality exhibited considerable competitive reactivity in the polymerizations of methyl acrylate and tert-butyl acrylate, resulting in mixed linear and branched macromonomers/macroinitiators. TGA analysis of α-norbornenyl macromonomers showed that the presence of norbornenyl functionality appreciably enhanced their thermal stability." @default.
- W2077055537 created "2016-06-24" @default.
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- W2077055537 date "2005-10-12" @default.
- W2077055537 modified "2023-10-09" @default.
- W2077055537 title "ATRP from a Norbornenyl-Functionalized Initiator: Balancing of Complementary Reactivity for the Preparation of α-Norbornenyl Macromonomers/ω-Haloalkyl Macroinitiators" @default.
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- W2077055537 doi "https://doi.org/10.1021/ma0515984" @default.
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