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- W2077066863 abstract "Reactions of Li(ER3)(thf)x(E = Si or Ge, R = SiMe3, thf = tetrahydrofuran) with gallium(III) chloride were carried out in diethyl ether with 1 : 1 and 2 : 1 stoichiometries. The 1 : 1 reactions gave products that decomposed upon recrystallization from pentane or drying in vacuo. The NMR spectra were consistent with a mixture of Li[R3SiGaCl3](thf)4(major) and GaCl2(SiR3)·thf (minor) in the case of E = Si and GaCl2(GeR3)·thf for E = Ge. The 2 : 1 E = Ge reactions gave a mixture of two products exhibiting needle and plate crystal morphologies. The NMR spectra and a partial structure determination identified the former as Li[R3GeGaCl3](thf)4. A full structure determination of the latter showed it to be the diethoxy-bridged dimer, (R3Ge)ClGa(µ-OEt)2GaCl(GeR3). The latter product is thought to result from cleavage of the ether solvent by either Ga2Cl6 or the intermediate gallium complex. Possible pathways are discussed." @default.
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- W2077066863 date "1996-01-01" @default.
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- W2077066863 title "Reactions of gallium(<scp>III</scp>) chloride with Li[E(SiMe<sub>3</sub>)<sub>3</sub>](E = Si or Ge): crystal structure of (R<sub>3</sub>Ge)ClGa(µ-OEt)<sub>2</sub>GaCl(GeR<sub>3</sub>)(R = SiMe<sub>3</sub>)" @default.
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- W2077066863 doi "https://doi.org/10.1039/dt9960004183" @default.
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