Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077067508> ?p ?o ?g. }
Showing items 1 to 63 of
63
with 100 items per page.
- W2077067508 endingPage "1478" @default.
- W2077067508 startingPage "1475" @default.
- W2077067508 abstract "Abstract The completeness of Am(III) electrochemical oxidation in 3–15 M H3PO4 depending on phosphoric acid and americium concentration, as well as the influence of H3PO4, americium concentration and temperature on Am(IV) stability in phosphoric acid solutions has been investigated. It has been found that in 3–8 M H3PO4 an Am(IV) disproportionation occurs according to the scheme: 3Am(IV) → 2Am(III)+Am(VI), and in solutions with H3PO4 concentration greater than 10 M—an Am(IV) reduction to Am(III). The apparent rate constant of Am(IV) disproportionation increases with H3PO4 concentration decrease; the rate constant of Am(IV) reduction increases with the decrease of americium concentration, phosphoric acid concentration (15-10M), and with the increase of temperature. The activation energy for the reaction Am(IV) → Am(III) in 12 M H3PO4 is 15·6 ± 1·1 kcal. mole−1. The mechanism of Am(IV) And Am(VI) formation during electrochemical oxidation of Am(III) is discussed." @default.
- W2077067508 created "2016-06-24" @default.
- W2077067508 creator A5009780361 @default.
- W2077067508 creator A5017271851 @default.
- W2077067508 creator A5046090005 @default.
- W2077067508 creator A5059850406 @default.
- W2077067508 creator A5065593082 @default.
- W2077067508 date "1975-06-01" @default.
- W2077067508 modified "2023-10-18" @default.
- W2077067508 title "Behaviour of americium(IV) in phosphoric acid solutions" @default.
- W2077067508 cites W1975822065 @default.
- W2077067508 cites W2000207687 @default.
- W2077067508 doi "https://doi.org/10.1016/0022-1902(75)80793-7" @default.
- W2077067508 hasPublicationYear "1975" @default.
- W2077067508 type Work @default.
- W2077067508 sameAs 2077067508 @default.
- W2077067508 citedByCount "11" @default.
- W2077067508 countsByYear W20770675082014 @default.
- W2077067508 countsByYear W20770675082019 @default.
- W2077067508 countsByYear W20770675082022 @default.
- W2077067508 crossrefType "journal-article" @default.
- W2077067508 hasAuthorship W2077067508A5009780361 @default.
- W2077067508 hasAuthorship W2077067508A5017271851 @default.
- W2077067508 hasAuthorship W2077067508A5046090005 @default.
- W2077067508 hasAuthorship W2077067508A5059850406 @default.
- W2077067508 hasAuthorship W2077067508A5065593082 @default.
- W2077067508 hasConcept C13965031 @default.
- W2077067508 hasConcept C177322064 @default.
- W2077067508 hasConcept C178790620 @default.
- W2077067508 hasConcept C179104552 @default.
- W2077067508 hasConcept C185592680 @default.
- W2077067508 hasConcept C2776622989 @default.
- W2077067508 hasConcept C540271850 @default.
- W2077067508 hasConcept C552554468 @default.
- W2077067508 hasConceptScore W2077067508C13965031 @default.
- W2077067508 hasConceptScore W2077067508C177322064 @default.
- W2077067508 hasConceptScore W2077067508C178790620 @default.
- W2077067508 hasConceptScore W2077067508C179104552 @default.
- W2077067508 hasConceptScore W2077067508C185592680 @default.
- W2077067508 hasConceptScore W2077067508C2776622989 @default.
- W2077067508 hasConceptScore W2077067508C540271850 @default.
- W2077067508 hasConceptScore W2077067508C552554468 @default.
- W2077067508 hasIssue "6" @default.
- W2077067508 hasLocation W20770675081 @default.
- W2077067508 hasOpenAccess W2077067508 @default.
- W2077067508 hasPrimaryLocation W20770675081 @default.
- W2077067508 hasRelatedWork W1984079266 @default.
- W2077067508 hasRelatedWork W2060480565 @default.
- W2077067508 hasRelatedWork W2076426214 @default.
- W2077067508 hasRelatedWork W2288402366 @default.
- W2077067508 hasRelatedWork W252695470 @default.
- W2077067508 hasRelatedWork W2588180264 @default.
- W2077067508 hasRelatedWork W4235324245 @default.
- W2077067508 hasRelatedWork W4238658791 @default.
- W2077067508 hasRelatedWork W4242560444 @default.
- W2077067508 hasRelatedWork W4255775103 @default.
- W2077067508 hasVolume "37" @default.
- W2077067508 isParatext "false" @default.
- W2077067508 isRetracted "false" @default.
- W2077067508 magId "2077067508" @default.
- W2077067508 workType "article" @default.